Table 1. List of Analyzed substance’s Names and Abbreviations, Analytical Methods, and LOQ.
substance family | analysis method | standard(s) | substances (abbreviation if applicable, limit of quantification—LOQ—in μg/kg dry mass) |
---|---|---|---|
hydrocarbons | GC–MS | SPIMFAB | C5–C8 aliphatics (10000), C8–C10 aliphatics (10000), C10–C12 aliphatics (10000), C12–C16 aliphatics (10000), C16–C35 aliphatics (10000), C8–C10 aromatics (2000), C10–C16 aromatics (1000), and C16–C35 aromatics (1000) |
PAHs | GC–MS | SPIMFAB | acenaphthene (Acen, 80), acenaphthylene (Acyl, 80), anthracene (A, 80), benzo[a]anthracene (BaA, 80), benzo[a]pyrene (BaP, 80), benzo[b]fluoranthene (BbF, 80), benzo[g,h,i]perylene (BPer, 80), benzo[k]fluoranthene (BkF, 80), chrysene (Chry, 80), dibenzo[a,h]anthracene (DahA, 80), fluoranthene (Fluo, 80), fluorene (F, 80), indeno[1,2,3-cd]pyrene (IP, 80), naphthalene (Nap, 80), phenanthrene (Phen, 80), and pyrene (Pyr, 80) |
BTEX / MTBE; chlorobenzenes; chlorinated aliphatics | GC−MS, GC−ECD (tetra−hexa chlorobenzenes) | US EPA 8260, US EPA 5021A, US EPA 5021, MADEP 2004, rev. 1.1 and ISO 15009, US EPA 8081 (tetra−hexa chlorobenzenes) | benzene (20), ethylbenzene (20), methyl tert-butyl ether (MTBE, 50), styrene (40), toluene (100), and sum of xylenes (15); monochlorobenzene (10), 1,2-dichlorobenzene (20), 1,3-dichlorobenzene (20), 1,4-dichlorobenzene (20), 1,2,3-trichlorobenzene (20), 1,2,4-trichlorobenzene (30), 1,3,5- trichlorobenzene (50), 1,2,3,4-tetrachlorobenzene (10), 1,2,3,5 + 1,2,4,5-tetrachlorobenzene (20), pentachlorobenzene (10), hexachlorobenzene (HclB, 5), diclobenil (10), and quintozene−pentachloroaniline sum (20); dichloromethane (800), 1,1-dichloroethane (10), 1,2-dichloroethane (100), 1,2-dichloropropane (100), trichloromethane (chloroform, 30), tetrachloromethane (10), hexachloroethane (10), 1,1-dichloroethene (10), cis-1,2-dichloroethene (20), trans-1,2-dichloroethene (10), 1,1,1-trichloroethane (10), 1,1,2-trichloroethane (40), trichloroethene (10), tetrachloroethene (20), and vinyl chloride (100) |
chlorophenols | GC–MS/GC-ECD | US EPA 8041, US EPA 3500, and DIN ISO 14154 | 2-monochlorophenol (20), 3-monochlorophenol (20), 4-monochlorophenol (20), 2,3-dichlorophenol (20), 2,4 + 2,5-dichlorophenol (40), 2,6-dichlorophenol (20), 3,4-dichlorophenol (20), 3,5-dichlorophenol (20), 2,3,4-trichlorophenol (20), 2,3,5-trichlorophenol (20), 2,3,6-trichlorophenol (20), 2,4,5-trichlorophenol (20), 2,4,6-trichlorophenol (20), 3,4,5-trichlorophenol (20), 2,3,5,6-tetrachlorophenol (20), 2,3,4,5-tetrachlorophenol (20), 2,3,4,6-tetrachlorophenol (20), and pentachlorophenol (PClPh, 20) |
aldehydes | HPLC | formaldehyde (100), acetaldehyde (200), propional (200), butanal (200), and glutaraldehyde (pentanedial, 200) | |
PCBs | GC–MS | DIN ISO 10382 | 2,4,4′-trichlorobiphenyl (PCB 28, 0.1), 2,2′,5,5′-tetrachlorobiphenyl (PCB 52, 0.1), 2,2′,4,5,5′-pentachlorobiphenyl (PCB 101, 0.1), 2,3′,4,4′,5′-pentachlorobiphenyl (PCB 118, 0.1), 2,2′,3,4,4′,5′-hexachlorobiphenyl (PCB 138, 0.1), 2,2′,4,4′,5,5′-hexachlorobiphenyl (PCB 153, 0.1), and 2,2′,3,4,4′,5,5′-heptachlorobiphenyl (PCB 180, 0.1) |
alkylphenolsa | GC–MS | 4-tert-octylphenol (OP, 10–130) and 4-nonylphenol (NP, 100–200) | |
phthalatesa | GC–MS | standard: DIN 19742 | dimethyl phthalate (DMP, 50), diethyl phthalate (DEP, 50), di-n-propyl phthalate (DPP, 50–120), di-n-butyl phthalate (DBP, 50–80), diisobutyl phthalate (DiBP, 50–110), di-n-pentyl phthalate (DNPP, 50), di-n-octyl phthalate (DNOP, 50–7000), di-2-ethylhexyl phthalate (DEHP, 50), butylbenzylphthalate (BBP, 50–200), dicyclohexyl phthalate (DCP, 50–60), diisodecyl phthalate (DIDP, 10000), diisononyl phthalate (DINP, 2500–100,000), and di-n-hexylphthalate (DNHP, 50–100) |
brominated flame retardantsa | LC–MS/MS | DIN 38414 | 2,4,4′-tribromodiphenyl ether (BDE 28, 0.032–0.48), 2,2′,4,4′-tetrabromodiphenyl ether (BDE 47, 0.16–0.5), 2,2′,4,4′,5-pentabromodiphenyl ether (BDE 99, 0.18–0.5), 2,2′,4,4′,6-penta-bromodiphenyl ether (BDE 100, 0.064–0.48), 2,2′,4,4′,5,5′-hexabromodiphenyl ether (BDE 153, 0.13–0.48), 2,2′,4,4′,5,6′-hexabromodiphenyl ether (BDE 154, 0.027–0.48), tetrabromobisphenol A (TBBP-A, 5), decabromobiphenyl (DeBB, 9–21), and hexabromocyclododecane (HBCD, 50) |
PFASs | LC–MS/MS | perfluoro-n-butanoic acid (PFBA, 0.5), perfluoro-n-pentanoic acid (PFPeA, 0.5), perfluoro-n-hexanoic acid (PFHxA, 0.5), perfluoro-n-heptanoic acid (PFHpA, 0.5), perfluoro-n-octanoic acid (PFOA, 0.5), perfluoro-n-nonanoic acid (PFNA, 0.5), perfluoro-n-decanoic acid (PFDA, 0.5), PFUnDA perfluoro-n-undecanoic acid (PFUnDA, 0.5), perfluoro-n-dodecanoic acid (PFDoDA, 0.5), perfluorobutanesulfonic acid (PFBS, 0.5), perfluorohexanesulfonic acid (PFHxS, 0.5), perfluoroheptanesulfonic acid (PFHpS, 0.5), perfluorooctanesulfonic acid (PFOS, 0.5), perfluorodecanesulfonic acid (PFDS, 0.5), perfluorooctanesulfonamide (FOSA, 0.5), 6:2 fluorotelomer sulfonate (6:2 FTS, 0.5), 8:2 fluorotelomer sulfonate (8:2 FTS, 0.5), perfluoro-n-tridecanoic acid (PFTrDA, 0.5), perfluoro-n-tetradecanoic acid (PFTeDA, 0.5), N-methyl perfluorooctane sulfonamide (MeFOSA, 0.5), N-ethyl perfluorooctane sulfonamide (EtFOSA, 0.5), N-methyl perfluorooctane sulfonamidoethanol (MeFOSE, 0.5), and N-ethyl perfluorooctane sulfonamidoethanol (EtFOSE, 0.5) | |
organotins | GC–MS | ISO 23161:2011 | monobutyltin (MBT, 1), dibutyltin (DBT, 1), tributyltin (TBT, 1), tetrabutyltin (TetBT, 1), monooctyltin (MOT, 1), dioctyltin (DOT, 1), tricyclohexyltin (TCHT, 1), monophenyltin (MPhT, 1), diphenyltin (DPhT, 1), and triphenyltin (TPhT, 1) |
pesticides | GC-ECD (organochlorine pesticides) and LC–MS/MS (other pesticides) | US EPA 8081 (organochlorine pesticides) and CSN EN 15637 (other pesticides) | acetamiprid (10), acetochlor (10), alachlor (10), aldicarb (10), aldicarb sulfone (10), aldicarb sulfoxide (10), aldrin (10), ametryn (10), atrazine (10), atrazine-desisopropyl (10), azoxystrobin (10), boscalid (10), cadusafos (10), carbaryl (10), carbendazim (10), carbofuran (10), carbofuran-3-hydroxy (10), chlorfenvinphos (10), chloridazon (10), chloridazon-desphenyl (10), chloridazon-methyldesphenyl (10), 6-chloronicotinic acid (10), chlorpyrifos (10), chlorsulfuron (10), chlortoluron (10), clomazone (10), clothianidin (10), cyanazine (10), cyproconazole (10), atrazine-desethyl (10), terbuthylazine-desethyl (10), atrazine-desisopropyl (10), o,p′-DDD (10), p,p′-DDD (10), o,p′-DDE (10), p,p′-DDE (10), o,p′-DDT (10), p,p′-DDT (10), desmetryn (10), diazinon (10), difenacoum (10), diflufenican (10), dichlorvos (10), dicrotophos (10), dieldrin (10), dimethoate (10), dimoxystrobin (10), diuron (10), endrin (10), alpha-endosulfan (10), epoxiconazole (10), fenoxycarb (10), fipronil (10), fipronil sulfone (10), fluazifop (10), fonofos (10), phorate (10), phosalone (10), phosphamidon (10), phosmet (10), phosmet oxon (10), heptachlor (10), cis-heptachlor epoxide (10), trans-heptachlor epoxide (10), hexazinone (10), alpha-HCH (10), beta-HCH (10), gamma-HCH (lindane, 10), 2-hydroxyatrazine (10), hydroxy-terbutylazine (10), imidacloprid (10), imidacloprid olefin (10), imidacloprid urea (10), indoxacarb (10), isodrin (10), isoproturon (10), isoproturon-desmethyl (10), isoproturon-monodesmethyl (10), kresoxim-methyl (10), linuron (10), malaoxon (10), malathion (10), metamitron (10), metazachlor (10), methidathion (10), methiocarb (10), methiocarb sulfone (10), methiocarb sulfoxide (10), metconazole (10), metolachlor (isomers) (10), methomyl (10), methomyl oxime (10), metribuzin (10), oxamyl (10), pendimethalin (10), pethoxamid (10), pirimicarb (10), prochloraz (10), prometon (10), prometryn (10), propazine (10), propiconazole (10), propoxur (10), pyrimethanil (10), sebuthylazine (10), simazine (10), simazine-2-hydroxy (10), simetryn (10), tebuconazole (10), telodrin (10), terbuthylazine-desethyl-2-hydroxy (10), terbutryn (10), terbuthylazine (10), thiacloprid (10), and thiamethoxam (10) |
The LOQs varied between samples due to matrix effects, so their ranges are presented.