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. 2021 Feb 22;11(5):2999–3008. doi: 10.1021/acscatal.0c04374

Table 3. Cycloisomerization of S3 Using Recycled C1 and C2a.

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entry catalyst NMR yield (%)
1 C1 90
2 C2 77
3b C1 99
4b C2 95
5c C1 >99
6c C2 >99
a

Reaction conditions: 0.4 mmol of S3, 0.08 mmol of triethylamine, 0.012 mmol of Pd(II)-AmP-MCF, and 1 mL of toluene. The NMR yield was determined using 1,3,5-trimethoxybenzene as the internal standard.

b

1 mol % BQ used to reactivate the catalyst before the reaction.

c

1 mol % BQ added at the beginning of the reaction.