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. 2021 Mar 1;60(6):3749–3760. doi: 10.1021/acs.inorgchem.0c03498

Table 3. Composition and Lattice Type of the Solid Solutions Made from [Ag(NH3)2]NO3 and (K,Na)(MnO4,ClO4) Solutions.

permanganate used solution-phase ClO4/MnO4 ratio ClO4/MnO4 ratio in the solid solution crystal structure
KMnO4 99:1 97:3 orthorhombic
KMnO4 95:5 86:14 orthorhombic
KMnO4 92:8 72:28 orthorhombic + monoclinic
KMnO4 90:10 69:31 monoclinic
KMnO4 70:30 62:38 monoclinic
KMnO4 50:50 26:74 monoclinic
NaMnO4 30:70 23:77 monoclinic
NaMnO4 10:90 05:95 monoclinic