Table 2.
Excess Gibbs free energy of mixing () of liquid Li–Mg alloy at temperatures 1000 K, 1300 K, 1600 K, 1900 K and 2200 K.
| XMg | Excess Gibbs free energy of mixing () in (J/mol) |
|||||||
|---|---|---|---|---|---|---|---|---|
| T = 1000K |
T = 1300 K |
|||||||
| Linear fit | Expon. fit | Experimental [25] | Wang et al. [19] | Cost 507 [20] | Linear fit | Expon. fit | Wang et al. [19] | |
| 0.1 | -2095.23 | -1557.95 | -2085.82 | -1369.21 | -466.40 | -2336.12 | -1515.10 | -1426.77 |
| 0.2 | -3562.91 | -2828.97 | -3540.46 | -2573.13 | -801.39 | -3797.62 | -2738.52 | -2701.48 |
| 0.3 | -4434.11 | -3790.56 | -4405.72 | -3517.11 | -1018.03 | -4533.01 | -3649.81 | -3719.74 |
| 0.4 | -4756.84 | -4400.12 | -4740.12 | -4130.82 | -1127.89 | -4682.10 | -4218.27 | -4401.44 |
| 0.5 | -4596.06 | -4611.78 | -4598.00 | -4368.23 | -1141.00 | -4376.03 | -4413.21 | -4690.79 |
| 0.6 | -4033.70 | -4393.37 | -4050.42 | -4207.57 | -1065.87 | -3737.25 | -4214.18 | -4556.28 |
| 0.7 | -3168.61 | -3743.26 | -3193.52 | -3651.43 | -909.50 | -2879.53 | -3621.17 | -3990.71 |
| 0.8 | -2116.63 | -2707.32 | -2135.98 | -2726.63 | -677.35 | -1907.93 | -2664.87 | -3011.16 |
| 0.9 | -1010.52 | -1395.74 | -1019.92 | -1484.34 | -373.38 | -918.85 | -1416.90 | -1659.03 |
| XMg | Excess Gibbs free energy of mixing () in (J/mol) |
||||||||
|---|---|---|---|---|---|---|---|---|---|
| T = 1600 K |
T = 1900 K |
T = 2200 K |
|||||||
| Linear fit | Expon. fit | Wang et al. [19] | Linear fit | Expon. fit | Wang et al. [19] | Linear fit | Expon. fit | Wang et al. [19] | |
| 0.1 | -2577.0 | -1467.9 | -1484.3 | -2817.9 | -1417.9 | -1541.9 | -3058.8 | -1366.3 | -1599.4 |
| 0.2 | -4032.3 | -2643.0 | -2829.8 | -4267.0 | -2545.0 | -2958.2 | -4501.8 | -2446.5 | -3086.5 |
| 0.3 | -4631.9 | -3508.2 | -3922.4 | -4730.8 | -3367.9 | -4125.0 | -4829.7 | -3230.3 | -4327.6 |
| 0.4 | -4607.4 | -4041.8 | -4672.1 | -4532.6 | -3871.3 | -4942.7 | -4457.9 | -3707.0 | -5213.3 |
| 0.5 | -4156.0 | -4223.2 | -5013.4 | -3936.0 | -4041.3 | -5335.9 | -3715.9 | -3867.3 | -5658.5 |
| 0.6 | -3440.8 | -4039.3 | -4905.0 | -3144.4 | -3869.8 | -5253.7 | -2847.9 | -3706.1 | -5602.4 |
| 0.7 | -2590.4 | -3490.9 | -4330.0 | -2301.3 | -3357.4 | -4669.3 | -2012.3 | -3223.9 | -5008.6 |
| 0.8 | -1699.2 | -2598.4 | -3295.7 | -1490.5 | -2518.0 | -3580.2 | -1281.8 | -2430.1 | -3864.8 |
| 0.9 | -827.2 | -1408.5 | -1833.7 | -735.5 | -1381.9 | -2008.4 | -643.8 | -1344.5 | -2183.1 |