Table 1.
Selected bond distances (Å) and bond angles (°) for complexes Ag1–3.
| Distance (Å) | Ag1 | Distance (Å) | Ag2 | Ag3 | |
|---|---|---|---|---|---|
| Ag1–O1 | 2.360(2) | Ag1–O1 | 2.555(2) | 2.449(4) | |
| Ag1–O2 | 2.328(2) | Ag1···O2 ii | 2.645(2) | – | |
| Ag1–S1 | 2.6198(7) | Ag1–N1 | 2.200(2) | 2.186(3) | |
| Ag1–S2 i | 2.6747(8) | Ag1–N2 i | 2.218(2) | 2.184(3) | |
| Ag1···Ag1 i | 2.7871(5) | 2.7235(6) | |||
| Angle (°) | Angle (°) | ||||
| O1–Ag1–O2 | 108.07(7) | O1–Ag1–N1 | 112.75(8) | 91.94(14) | |
| O1–Ag1–S1 | 105.18(5) | O1–Ag1–N2 i | 82.66(8) | 96.78(14) | |
| O2–Ag1–S1 | 124.24(5) | N1–Ag1–N2 i | 164.29(10) | 169.76(12) | |
| O1–Ag1–S2 i | 103.56(5) | ||||
| O2–Ag1–S2 i | 121.54(5) | ||||
| S1–Ag1–S2 i | 91.44(2) |
Symmetry codes for Ag1: (i) 1 + x, y, z; for Ag2: (i) 1 − x, 1 − y, 1 – z; (ii) 1 − x, 2 − y, 1 – z; for Ag3: (i) 1 − x, 1 − y, 2 − z.