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Positions and redox reactions associated with observed cathodic and anodic peaks in cyclic voltammograms of complexes Ag1–3 recorded at GC electrode in DMSO and 0.1 M TBAHP as a supporting electrolyte with a scan rate of 50 mV/s.
| Silver(I) Complex | Oxidation Process (E, V) | Reduction Processes (E, V) | |
|---|---|---|---|
| Ag(I)→Ag(II) | Ag(II)→Ag(I) | Ag(I)→Ag(0) | |
| Ag1 | +1.25 | −0.43 | −1.26 |
| Ag2 | +1.38 | −0.27 | −0.92 |
| Ag3 | +1.12 | −0.19 | -0.82 |
