Table 2. Photophysical Properties of the Molecules in 1 wt % ZEONEX Films.

emitter	1CT/eVa	3LE/eVb	ΔEST/eVc	ΦPLd	τp/nse	eτd/mse
TPA-ace	2.99	2.53	0.46	0.37
TPA-ace-Br	2.77	2.51	0.26		8.05	0.33 (90.6%)
						2.05 (9.4%)
2TPA-ace	2.95	2.55	0.40	0.36	1.93 (92.1%)
					4.39 (7.9%)
TPA-ace-CN	2.99	2.47	0.52	0.20	2.55 (97.0%)
					7.50 (3.0%)
TPA-ace-TRZ	2.94	2.46	0.48	0.12	6.9 (73%)
					24.7 (27%)

^aValues estimated from the onset of time-resolved PL spectra after the stabilization of ¹CT or deconvoluted in order to obtain only the ¹CT onset (Figure S42).

^bValues estimated from the onset of phosphorescence spectra. Spectra were collected with an 80 ms time delay and measured at 80 K.

^cΔE_ST = ¹CT – ³LE.

^dΦ_PL measured for spin-coated films with a concentration of 1 wt % in the ZEONEX matrix using an integrating sphere connected to a Fluorolog-3.

^eLifetimes estimated from monoexponential and biexponential decay fitting of the prompt and delayed regimes, respectively (Figure S46).