. 2021 Mar 23;33(7):2408–2419. doi: 10.1021/acs.chemmater.0c04491

Table 1. Summary of A₄M^IIISb^VX₁₂ Phases.

composition	space group	a	c	Abs max (nm)	ref.
Cs₄Sb^IIISb^VCl₁₂	I4₁/amd	10.4650 (2)	21.0095 (7)	540.5	(19,24,25)
Cs₄Bi^IIISb^VCl₁₂	I4₁/amd	10.492 (2)	21.1017 (6)	417	(24,25)
Cs₄In^IIISb^VCl₁₂	Fm-3m	9.9093 (1)^a		590	(19,24)
Rb₄Sb^IIISb^VBr₁₂	I4₁/amd	10.706 (3)^a	21.695 (22)	“black”	(21,23)
Rb₄In^IIISb^VCl₁₂	Fm-3m	10.0613 (1)^a			(24)
Cs₄Sb^IIISb^VBr₁₂	I4₁/amd	10.842 (3)	21.91 (15)	“black”	(18,24,26)
(NH₄)₄Sb^IIISb^VBr₁₂	I4₁/amd	10.66	21.52	1053	(21,25,27)
“Rb₄Sb^IIISb^VCl₁₂”		10.14 (2)		510.2	(19,21,25)

Value at 4.7 K.

Table 1. Summary of A4MIIISbVX12 Phases.