Table 1. ¹H and ¹³C NMR Assignments of the Mannan_P.arc^a.

sugar residue	1H/13C (ppm) 1JC1, H1
	1	2	3	4	5	6
A	5.19	4.01	3.80	3.62	3.66	3.64–3.80
2-Manp	101.8	79.8	71.5	68.1	74.4	62.3
	175
B	5.04	3.96	3.75	3.53	3.66	3.64–3.78
t-Manp	103.5	71.3	71.6	68.2	74.5	62.4
	176
C	5.01	3.93	3.83	3.73	3.72	3.57–3.91
2,6-Manp	99.4	80.0	71.4	67.8	72.1	66.9
	180
D	4.99	3.91	3.81	3.73	3.72	3.57–3.91
2,6-Manp	99.4	80.0	71.5	67.8	72.1	66.9
	180
E	4.94	3.96	3.70	3.53	3.66	3.64–3.78
t-Manp	103.4	71.3	71.7	68.1	74.4	62.4
	174
F	4.93	4.11	3.85	3.64	3.70	3.64–3.78
3-Manp	103.5	70.9	79.2	67.6	72.5	62.4
	174
G	4.79	3.88	3.72	3.59	3.63	3.67–3.84
6-Manp	100.6	71.3	72.1	68.1	72.1	66.7
	172
H	5.34	3.91	3.88	3.68	n.d	n.d
1-P Manp	97.5	71.8	71.3	67.6
	174
I	4.36	3.17	3.45	3.69	3.67	3.64–3.78
t-Glcp	102.9	74.0	74.9	71.8	77.5	62.4
	163

^aSpectra were recorded in D₂O at 298 K at 600 MHz using acetone as external standard (δ_H/δ_C 2.25/31.45 ppm).