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. Author manuscript; available in PMC: 2021 Apr 15.
Published in final edited form as: Chem Phys Lett. 2002 Feb 7;191(1-2):47–53. doi: 10.1016/0009-2614(92)85366-i

Table 1.

Maximum differential polarized phase angles of an isotropic rotator and one- or two-photon excitation

r0 β (deg)a) Δ0 (deg)b)
one-photon excitation
0.4 0 30
0.1 45 8.21
0.0 54.74 0
−0.2 90 −19.5
two-photon excitation
0.57 0 41.8
0.143 45 11.54
0.0 54.74 0
−0.286 90 −30
a)

Angle between the absorption and emission transition moments.

b)

Phase shift in degrees between the horizontally and vertically polarized components of the emission, according to eq. (18).