. 2021 Apr 5;11(8):4784–4798. doi: 10.1021/acscatal.0c05027

Table 1. Cobalt-Time-Yield (CTY), Product Selectivities, and Hydrocarbon Chain-Growth Probability (α) for Co-Based FT-Catalysts Supported on a Multimodal Meso-Macroporous γ-Al₂O₃ Support, and Optionally Modified with Various Alkali and Lanthanide Oxide Promoters^a.

catalyst	CTY^b [mmol CO g_Co⁻¹ h⁻¹]	S(CO₂) [C%]	S(CH₄) [C%]	S(C₅₊) [C%]	S(C_5–10 Olef.) [C%]	α^c [-]	C_2–4 Olef.^d [%]	C_5–10 Olef.^e [%]
CoRu/AOmM	88.9	0.6	7.9	79.2	13.3	0.80	56.5	54.7
1.0Na-CoRu/AOmM	32.9	1.0	8.0	76.0	14.4	0.77	54.3	56.2
3.0Na-CoRu/AOmM	8.5	8.1	10.8	53.2	10.1	0.66	36.1	53.1
1.0K-CoRu/AOmM	27.5	1.3	8.6	74.4	13.9	0.78	54.1	57.2
1.0Cs-CoRu/AOmM	10.9	2.9	11.4	65.0	12.1	0.71	56.7	54.6
1.0La-CoRu/AOmM	43.1	0.8	8.2	73.2	16.2	0.75	54.7	58.1
1.0Pr-CoRu/AOmM	36.7	0.9	8.4	70.2	19.9	0.75	57.5	61.5
3.0Pr-CoRu/AOmM	12.4	1.3	12.4	54.6	19.5	0.66	53.0	61.7
1.0Sm-CoRu/AOmM	47.3	1.1	9.2	73.6	14.6	0.76	54.8	53.2

Reaction conditions: T = 473 K, P = 20 bar, H₂/CO = 2, WHSV = 5.1–11.0 h^–1, CO conversion = 20 ± 3%.

Cobalt-time-yield.

Chain-growth probability.

Molar olefin abundance within the C_2–4 hydrocarbon product fraction.

Molar olefin abundance within the C_5–10 hydrocarbon product fraction.

Table 1. Cobalt-Time-Yield (CTY), Product Selectivities, and Hydrocarbon Chain-Growth Probability (α) for Co-Based FT-Catalysts Supported on a Multimodal Meso-Macroporous γ-Al2O3 Support, and Optionally Modified with Various Alkali and Lanthanide Oxide Promotersa.