| Crystal data |
| Chemical formula |
C20H19N3O2
|
C22H21N3O |
|
M
r
|
333.38 |
343.42 |
| Crystal system, space group |
Monoclinic, P21/c
|
Monoclinic, P21/c
|
| Temperature (K) |
150 |
150 |
|
a, b, c (Å) |
13.8467 (3), 15.8409 (3), 8.0225 (2) |
14.3493 (8), 15.7501 (9), 8.3737 (5) |
| β (°) |
104.814 (1) |
106.285 (2) |
|
V (Å3) |
1701.20 (7) |
1816.55 (18) |
|
Z
|
4 |
4 |
| Radiation type |
Cu Kα |
Cu Kα |
| μ (mm−1) |
0.69 |
0.62 |
| Crystal size (mm) |
0.19 × 0.11 × 0.07 |
0.19 × 0.13 × 0.08 |
| |
| Data collection |
| Diffractometer |
Bruker D8 VENTURE PHOTON 100 CMOS |
Bruker D8 VENTURE PHOTON 100 CMOS |
| Absorption correction |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
|
T
min, T
max
|
0.88, 0.95 |
0.86, 0.95 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
13222, 3372, 2939 |
13875, 3665, 3140 |
|
R
int
|
0.031 |
0.031 |
| (sin θ/λ)max (Å−1) |
0.625 |
0.625 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.036, 0.095, 1.05 |
0.037, 0.092, 1.04 |
| No. of reflections |
3372 |
3665 |
| No. of parameters |
303 |
320 |
| H-atom treatment |
All H-atom parameters refined |
All H-atom parameters refined |
| Δρmax, Δρmin (e Å−3) |
0.23, −0.19 |
0.17, −0.16 |
