Table 1.
Position | 1 (DMSO-d6) | Position | 2 (CDCl3) | ||
---|---|---|---|---|---|
δC, Type | δH (J in Hz) | δC, Type | δH (J in Hz) | ||
1 | 156.6, C | 1 | 118.0, CH | 6.94 (d, J = 8.5 Hz) | |
2 | 122.6, C | 2 | 134.8, CH | 7.72 (d, J = 8.5 Hz) | |
3 | 143.2, C | 3 | 134.0, C | ||
4 | 123.5, CH | 6.28 (s) | 4 | 156.9, C | |
4a | 150.6, C | 4a | 121.6, C | ||
4b | 153.5, C | 5 | 166.4, C | ||
5 | 111.7, CH | 5.90 (d, J = 2.0 Hz) | 7 | 69.1, CH2 | 5.11 (s) |
6 | 165.6, C | 7a | 125.9, C | ||
7 | 101.3, CH | 6.19 (d, J = 2.0 Hz) | 8 | 121.2, CH | 6.40 (s) |
8 | 163.3, C | 9 | 135.6, C | ||
8a | 109.7, C | 10 | 117.8, CH | 6.87 (s) | |
8b | 114.1, C | 11 | 147.4, C | ||
9 | 45.6, C | 11a | 141.0, C | ||
10 | 190.2, C | 12a | 154.0, C | ||
11 | 167.5, C | 13 | 64.3, CH3 | 3.91 (s) | |
12 | 19.8, CH3 | 2.10 (s) | 1’ | 190.7, C | |
1’/8’ | 125.9, C | 2’ | 124.1, CH | 6.66 (s) | |
2’/7’ | 115.5, CH | 6.15 (s) | 3’ | 158.8, C | |
3’/6’ | 144.1, C | 4’ | 21.7, CH3 | 2.26 (s) | |
4’/5’ | 131.0, C | 5’ | 28.3, CH3 | 2.01 (s) | |
4’a/4’b | 137.3, C | 1’’ | 21.0, CH3 | 2.25 (s) | |
8’a/8’b | 117.7, C | ||||
9’/10’ | 19.9, CH3 | 1.34 (s) | |||
3’/6’-OH | 8.95 (s) | ||||
4’/5’-OH | 9.00 (s) |