Table 1.
Performance of Membrane Separation for Mercury and Heavy metals.
Membrane | Mixture Components |
Separation Conditions | Rejection % or Removal % |
Ref. |
---|---|---|---|---|
Two micro-porous PP supported membrane loaded with a mixed N/O/S-donor |
Ag+ and Hg2+ | Na2S2O3 (0.04 M) and EDTA disodium salt (0.025 M) as stripping agents in 3.5 h | 95.3% Ag+ and 94.7% Hg2+ | [75] |
30% cellulose triacetate (CTA), 60% 2-nitrophenyl octyl ether (NPOE), and 10% w/w
Cyanex 471 |
HgCl2 |
Hg [2+] in HCl + NaCl at pH 12. |
81 % | [82] |
D2EHPA (CAS No. 298-07-7) with 98.5% purity |
HgCl2 | 1 M H2SO4 with 0.5 M thiourea | 92% | [84] |
polyethyleneimine (PEI) | Hg in a heavy metal mixture | pH 5.5 cadmium/polymer ratio about 0.35 mercury/polymer ratio about 0.39 | 98% Hg and 97% Cd | [99] |
1,1,7,7-tetraethyl 4(tetradecyl)diethylenetriamine (TE14DT) |
Cd2+/Pb2+ and Hg2+/
Cu2+ mixtures |
pH 2.5 | 90% | [100] |
poly(benzylsulfone) | Hg2+ | Diluted in hydrochloric acid | >90% | [101] |
Mixed-matrix membranes (sorbent particles and polysulfone) | Ca2+, Ag+, Hg2+ | Diluted in HCl at pH 4 | 95% Hg2+ | [102] |
Cyanex 302 (bis(2,4,4-trimethyl- pentyl)thiophosphinic acid) in kerosene | Cu2+ and Hg2+ | Diluted in phosphoric acid slurry | 70% | [96] |
Mn/Mo/Ru/Al2O3 membrane | Hg | Diluted in hydrochloric acid | 95% | [97] |
Polyvinylamine | mercury - sodium chloride and sulfate | feed mercury concentration range tested (0–50 ppm) | 99% | [98] |
Cross flow membrane filtration cell (CF 042, Sterlitech, California) | Hg2+ | higher operating pressures (≥34.5 bar) | 95% | [103] |