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. 2021 Apr 8;11(4):269. doi: 10.3390/membranes11040269

Table 1.

Performance of Membrane Separation for Mercury and Heavy metals.

Membrane Mixture
Components
Separation Conditions Rejection %
or Removal %
Ref.
Two micro-porous PP supported membrane loaded with a mixed
N/O/S-donor
Ag+ and Hg2+ Na2S2O3 (0.04 M) and EDTA disodium salt (0.025 M) as stripping agents in 3.5 h 95.3% Ag+ and 94.7% Hg2+ [75]
30% cellulose triacetate (CTA), 60% 2-nitrophenyl octyl ether (NPOE), and 10% w/w
Cyanex 471
HgCl2 Hg [2+] in HCl + NaCl at
pH 12.
81 % [82]
D2EHPA (CAS No. 298-07-7) with
98.5% purity
HgCl2 1 M H2SO4 with 0.5 M thiourea 92% [84]
polyethyleneimine (PEI) Hg in a heavy metal mixture pH 5.5 cadmium/polymer ratio about 0.35 mercury/polymer ratio about 0.39 98% Hg and 97% Cd [99]
1,1,7,7-tetraethyl 4(tetradecyl)diethylenetriamine (TE14DT) Cd2+/Pb2+ and Hg2+/
Cu2+ mixtures
pH 2.5 90% [100]
poly(benzylsulfone) Hg2+ Diluted in hydrochloric acid >90% [101]
Mixed-matrix membranes (sorbent particles and polysulfone) Ca2+, Ag+, Hg2+ Diluted in HCl at pH 4 95% Hg2+ [102]
Cyanex 302 (bis(2,4,4-trimethyl- pentyl)thiophosphinic acid) in kerosene Cu2+ and Hg2+ Diluted in phosphoric acid slurry 70% [96]
Mn/Mo/Ru/Al2O3 membrane Hg Diluted in hydrochloric acid 95% [97]
Polyvinylamine mercury - sodium chloride and sulfate feed mercury concentration range tested (0–50 ppm) 99% [98]
Cross flow membrane filtration cell (CF 042, Sterlitech, California) Hg2+ higher operating pressures (≥34.5 bar) 95% [103]