Table 5.
Analytical Technique | Sample | Recovery [%] | Intra/Inter-Day Variation [%] | LOD | LOQ | Detected Compounds in Real Samples | Ref |
---|---|---|---|---|---|---|---|
LC-DAD | apricot seeds | 91 ± 10 | 0.8/3.8 | 1.2 mg·L−1 | 4.0 mg·L−1 | bitter seeds 26 ± 14 mg·g−1 sweet seeds 0.16 ± 0.09 mg·g−1 |
[82] |
apricot liqueur | - | - | - | - | 38.79 µg·mL−1 | [83] | |
cherry liqueur | 16.08 µg·mL−1 | ||||||
HPLC–MS/MS | almonds | - | - | 200 µg·g−1 | - | <LOD | [22] |
HPLC-UV | plum seeds | - | - | - | - | 25.30 g 100 g−1 | [59] |
almonds | - | 0.13/0.75 | 2 µg·mL−1 | - | 4.51 ± 0.04% | ||
loquat fruit kernel | - | - | - | - | 7.58 ± 0.76 mg·g−1 | ||
almonds | 98.4–102.9 | 0.25/0.31 | 0.02 mg·L−1 | 0.07 mg·L-1 | sweet: <350 mg·kg−1 bitter: 14,700–50,400 mg·kg−1 |
[60] | |
peach seeds | 99.05 | 0.19 | 0.03 mg 100 g−1 | 0.09 mg 100 g−1 | 6.3 ± 0.2 g 100 g−1 | [84] | |
plum seeds | 0.439 ± 0.001 g 100 g−1 | ||||||
apricot seeds | 7.9 ± 0.2 g 100 g−1 | ||||||
peach seeds | - | - | - | - | seed: 12.14 ± 4.80 mg 100g−1 | [19] | |
citrullus colocynth kernels | 97.34 ± 0.58 | - | 0.88 mg·L−1 | 2.93 mg·L−1 | 0.27 ± 0.03 100 g−1 | [72] | |
apples | - | 0.095 | 0.0505 mg·g−1 | 0.0548 mg·g−1 | 0.28–1.40 mg·g−1 | [73] | |
Armeniacae semen | 98.0–102.6 | - | - | - | 45.42 ± 1.21 mg·g−1 | [85] | |
bitter almond oil | 96.0–102.0 | 4.8/7.2 | 0.07 µg·mL−1 | - | 0.092 ± 0.003 mg·g−1 | [86] | |
wild almond oil | - | - | - | - | 12.8–12.9 mg/100 mL oil | [87] | |
sweet apricot kernels | - | - | - | - | 5.0 ± 0.23 mg·g−1 | [88] | |
HPLC-DAD | apricot seeds | - | - | - | - | 0.861 g·100 g−1 | [56] |
almonds | - | - | - | - | 0.37–1.46 g·kg−1 | [89] | |
apple seeds | 98 | - | 0.1 µg·mL−1 | - | 1–3.9 mg·g−1 | [66] | |
apricots | - | - | 0.1 µg·mL−1 | 0.3 µg·mL- | 14.37 ± 0.28 mg·g−1 | [67] | |
cherries | 2.68 ± 0.02 mg·g−1 | ||||||
peaches | 6.81 ± 0.02 mg·g−1 | ||||||
pears | 1.29 ± 0.04 mg·g−1 | ||||||
cucumbers | 0.07 ± 0.02 mg·g−1 | ||||||
courgettes | 0.21 ± 0.13 mg·g−1 | ||||||
melons | 0.12 ± 0.07 mg·g−1 | ||||||
apricot kernels | - | - | 0.2 µg·mL−1 | - | - | [69] | |
apricot kernels | 99.08 | 2.4/3.5 | - | - | 0.217–0.284 mg·mL−1 | [58] | |
plum seeds | - | - | 1.06 μg·mL−1 | 3.49 μg·mL−1 | 25.30 g 100 g−1 | [65] | |
bayberry kernels | 77.9 | - | - | - | 129.13–358.68 mg·L−1 | [57] | |
food suplements | 94.81 | 0.57/1.52 | 0.13 mg·L−1 | 0.40 mg·L−1 | 20.68 ± 1.58 mg·g−1 | [86] | |
apricot kernels | 91 | 0.8/3.8 | 1.2 mg·L−1 | 4.0 mg·L−1 | 26 ± 14 mg·g−1 | [90] | |
UHPLC-(ESI)QqQ MS/MS | nonbitter almonds | - | - | 0.1 ng·mL−1 | 0.33 ng·mL−1 | 63.13 ± 57.54 mg·kg−1 | [64] |
semibitter almonds | 992.24 ± 513.04 mg·kg−1 | ||||||
bitter almonds | 40,060.34 ± 7855.26 mg·kg−1 | ||||||
alomnds | - | - | - | - | 1.62–76.50 mg·kg−1 | [67] | |
Spectrophotometric method | cassava root | - | - | - | - | 3.40 mg·L−1 | [80] |
cassava roots | - | - | - | - | 8.84–48.33 mg·g−1 | [91] | |
sorghum seeds | 122.31 mg·g−1 | ||||||
mango seeds | 4.41 mg·g−1 | ||||||
watermelon seeds | 3.97 mg·g−1 | ||||||
almond seeds | 3.91 mg·g−1 | ||||||
ELISA | black cherries | 99 ± 1.2 | - | 200 ± 0.05 pg·mL−1 | - | 2.14 ± 0.15 mg·g−1 | [92] |
yellow plums | 2.30 ± 0.90 mg·g−1 | ||||||
peaches | 5.79 ± 0.83 mg·g−1 | ||||||
black plums | 9.75 ± 1.32 mg·g−1 |
- no data.