Table 1.
List of lignin samples used in the flexible PU foam formulations and their measured properties.
No. | Process | Source | ID | Hydroxyl Content a (mmol/g) | Mn (Da) |
Mw (Da) |
PDI | Tg (°C) |
---|---|---|---|---|---|---|---|---|
1 | Kraft | Softwood | 1-K-SW | 5.61 | 1990 | 6580 | 3.31 | 149 |
2 | Organosolv | Hardwood | 2-O-HW | 4.56 | 1280 | 3440 | 2.69 | 104 |
3 | Organosolv | Corn Stover | 3-O-CS | 3.90 | 1750 | 6240 | 3.57 | 143 |
4 | Kraft | Softwood | 4-K-SW | 5.92 | 1770 | 6070 | 3.43 | 148 |
5 | Organosolv | Peanut Shell | 5-O-PS | 3.48 | 1640 | 9080 | 5.54 | 96 |
6 | Kraft | Softwood | 6-K-SW | 5.72 | 2030 | 8090 | 3.99 | 166 |
7 | Kraft | Softwood | 7-K-SW | 5.37 | 1750 | 5510 | 3.15 | 155 |
8 | Organosolv | Hardwood | 8-O-HW | 4.08 | 1640 | 4070 | 2.48 | 134 |
9 | Kraft | Softwood | 9-K-SW | 6.70 | 2080 | 6920 | 3.33 | 152 |
10 | Kraft | Bagasse | 10-K-BA | 4.63 | 2000 | 6550 | 3.28 | 147 |
11 | Kraft | Softwood | 11-K-SW | 6.42 | 1540 | 4290 | 2.79 | 148 |
12 | Kraft | Softwood | 12-K-SW | 5.22 | 2250 | 12100 | 5.38 | 158 |
13 | Kraft | Softwood | 13-K-SW | 3.49 | 2175 | 7280 | 3.35 | 138 |
14 | Organosolv | Hardwood | 14-O-HW | 5.19 | 1490 | 4250 | 2.85 | 84 |
15 | Kraft | Hardwood | 15-K-HW | 6.79 | 1030 | 1740 | 1.69 | 134 |
a: Hydroxyl content is based on the total OH content of lignin (Aliphatic OH + Ph-OH and –COOH).