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. 2021 Apr 13;8(Pt 3):444–454. doi: 10.1107/S2052252521002852

Table 4. Temperatures at which the metastable phase, the Sb phase or the ZnSb phase appear and disappear in the five Ag-doped thin films.

Film sample ZSA1_RT ZSA1_423K ZSA1_473K ZSA2 ZSA3
Target (Zn0.99Ag0.01)4Sb3 Zn0.99Ag0.01Sb Zn0.98Ag0.02Sb
Film composition (Zn+Ag):Sb = 58:42 = 1.38 (Zn+Ag):Sb = 45:55 = 0.82
T max (K) 573 573 573 573 573
   
Metastable phase  
T appear (K) 480 478 484 499 497
T disappear (K) 548 555 554 548 546
   
Sb  
T appear (K) 497 499 498 499 497
T disappear (K) 546 555 554
T reappear (K) 573 573 573
   
ZnSb  
T appear (K) 539 548 547 541 533