Table I.
Chemical shifts of types of resonances of glycans attached to native CEACAM1-IgV
| Attached to: | Name | H1, C1 | H2, C2 | H3, C3 | H4, C4 | H5, C5 | H6, C6 |
|---|---|---|---|---|---|---|---|
| Asn | β-GlcNAc | 5.06, 78.61 | 3.82, 54.19 | 3.62, 74.35 | 3.49, 77.42 | 3.48, 69.46 | 3.76, 61.11 |
| β-GlcNAc | 5.03, 78.25 | 3.77, 54.19 | ND | 3.53, 77.53 | 3.52, 69.48 | 3.75, 60.51 | |
| 1-4 GlcNAc | β-GlcNAc | 4.79, 100.42 | ND | ND | ND | ND | ND |
| β-GlcNAc | 5.04, 102.29 | ND | ND | ND | ND | ND | |
| β-GlcNAc | 4.71, 95.09 | 3.74, 56.32 | 71.97 | ND | ND | ND | |
| 1-4 GlcNAc | β-Man | 4.91, 99.40 | 3.89, 69.92 | ND | ND | ND | ND |
| β-Man | 4.87, 100.02 | 4.14, 69.66 | 78.48 | ND | ND | ND | |
| α-Man | 5.10, 102.6 | 4.08, 70.24 | ND | ND | ND | ND | |
| α-Man | 5.08, 102.36 | 4.07, 70.16 | ND | ND | ND | ND | |
| α-Man | 5.05, 102.27 | 4.06, 69.99 | ND | ND | ND | ND | |
| Unspecified/overlap | α-Man | ND | ND | 3.85, 70.59 | 3.68, 66.78 | 3.66, 72.84 | 3.74, 60.44 |
ND, not determined. Italics represents shifts of clusters representing multiple nuclei.