Table 3.

Regression coefficient (linearity of calibration; r²), accuracy and precision from intra-day and inter-day measurements, recoveries, matrix effect results, and limit of detection (LOD) for 121 target compounds analyzed in this study.

No.	Synonym	r²	Accuracy and Precision (Intra-Day)						Accuracy and Precision (Inter-Day)						Recovery (%)						ME (%) 10 ng/mL	LOD (ng/mL)
			1 ng/mL		10 ng/mL		20 ng/mL		1 ng/mL		10 ng/mL		20 ng/mL		1 ng/mL		10 ng/mL		20 ng/mL
			RE/%	RSD/%	RE/%	RSD/%	RE/%	RSD/%	RE/%	RSD/%	RE/%	RSD/%	RE/%	RSD/%		RSD/%		RSD/%		RSD/%
1	PA	0.9875	−6.2	6.7	1.9	7.5	−3.6	5.1	−2.8	4.7	5.6	4.8	−0.85	1.8	106	7.9	112	10	93	6.5	−19	5.0
2	mMP	0.9923	−3.7	6.2	−11	9.5	0.55	2.5	−0.90	5.7	−7.2	4.0	1.7	1.5	94	1.0	92	3.8	95	4.4	31	0.052
3	mEP	0.9993	−8.8	8.3	−6.0	5.7	−5.5	6.0	−3.6	4.9	−3.5	1.8	−3.4	3.3	106	0.67	99	5.5	98	5.7	31	0.014
4	mIPrP	0.9991	−3.7	3.3	−12	9.6	−1.4	4.8	−2.3	1.7	−8.7	3.4	0.73	2.5	99	2.1	93	0.92	97	9.0	29	0.012
5	mPrP	0.9991	−5.9	6.2	−10	8.2	−1.8	5.2	−4.4	5.2	−7.2	4.3	0.27	3.8	98	4.1	94	4.3	94	3.7	32	0.106
6	mIBP	0.9985	−4.3	7.8	−13	9.1	9.6	8.4	0.91	4.4	−10	7.0	14	4.2	96	3.5	98	4.8	90	0.39	28	0.238
7	mBP	0.9985	−4.8	8.6	−13	9.0	−3.0	4.7	1.4	6.8	−11	6.7	−2.6	5.1	92	0.69	92	1.6	100	10	28	0.102
8	mPeP	0.9999	−3.6	5.8	−4.3	8.1	−9.7	9.0	−2.3	5.5	−2.2	7.9	−6.5	4.5	93	12	96	2.0	97	1.8	31	0.036
9	mHxP	0.9997	−1.3	5.3	−10	8.3	−5.5	7.2	−2.1	4.5	−7.0	4.7	−4.3	3.6	102	5.2	96	2.0	100	6.7	32	0.072
10	mCPP	0.9956	−10	5.6	−2.8	3.8	−1.1	2.0	−10	5.6	−1.2	2.3	−1.5	2.0	101	1.4	101	2.5	101	9.1	34	0.068
11	mBzP	0.9997	−11	8.9	−3.6	4.8	−2.5	7.4	−10	9.7	−2.0	3.8	−0.96	6.1	94	8.8	86	4.2	86	5.7	16	0.022
12	mHpP	0.9963	−4.5	5.8	−12	9.7	−5.0	5.6	−0.72	3.9	−9.5	4.0	−2.5	2.3	97	7.1	97	1.4	101	3.1	32	0.010
13	mOP	0.9983	−1.0	4.8	−6.5	5.6	−7.4	8.1	1.2	3.3	−4.4	3.9	−5.0	4.6	101	3.7	94	1.2	97	10	26	0.042
14	mEHP	0.9912	−4.8	5.1	−14	6.9	−4.6	7.9	−1.9	2.5	−10	3.9	−0.62	3.2	114	8.9	106	5.9	94	4.5	29	2.0
15	mEOHP	0.9996	−3.7	4.0	−11	8.6	−1.3	4.1	−1.8	1.7	−8.0	3.3	0.56	2.3	101	4.2	96	6.0	94	6.0	31	0.018
16	mEHHP	0.9995	0.98	5.6	−9.6	8.4	−0.74	4.0	1.6	6.0	−6.2	5.1	0.99	2.8	101	2.2	98	5.2	100	4.5	30	0.012
17	mIDP	0.9998	−2.0	6.2	3.1	5.0	0.73	3.8	−0.62	5.3	2.2	4.0	2.0	3.1	94	2.2	84	2.1	85	1.6	14	0.020
18	mECPP	0.9972	−9.6	9.4	−5.4	3.7	−12	8.0	−3.5	3.6	−3.9	3.1	−12	7.3	107	0.66	86	5.9	98	6.1	32	0.060
19	mCMHP	0.9948	2.3	7.5	4.6	6.1	−2.4	4.9	3.1	3.6	−1.6	4.6	1.2	5.1	105	4.7	98	9.5	103	5.0	29	0.020
20	mCHpP	0.9992	−9.4	6.3	−4.4	7.0	−0.46	6.6	−7.2	4.9	−2.0	5.8	3.2	3.1	103	7.5	102	0.70	98	7.6	49	0.080
21	mCIOP	0.9998	−2.1	5.3	−14	4.6	−3.7	6.7	1.0	4.0	−8.5	5.3	−1.9	5.3	97	4.3	96	5.5	97	7.6	29	0.038
22	mCINP	0.9993	−4.6	4.5	−12	4.9	−3.3	5.8	−2.3	2.3	−7.1	4.7	−0.73	2.8	92	1.7	98	7.5	97	6.1	26	0.044
23	mHiDP	0.9982	−1.8	3.2	−11	7.4	−1.2	4.0	−0.17	1.8	−7.7	3.9	0.38	2.9	101	1.9	98	9.4	99	5.0	20	0.020
24	mHiNP	0.9970	−4.0	3.4	−6.5	8.6	−3.8	5.5	−3.8	2.7	−3.7	7.4	−0.87	3.3	88	3.1	97	8.2	95	9.2	22	0.034
25	mHNCH	0.9997	−6.4	5.4	−11	8.8	−7.6	8.3	−3.5	3.1	−8.5	4.1	−4.5	4.6	102	0.70	98	3.4	96	8.8	21	0.018
26	mONCH	0.9994	−4.3	6.2	−9.8	8.9	−10	7.4	−1.9	4.1	−5.4	3.6	−8.7	2.9	101	6.7	94	3.5	92	2.6	19	0.046
27	mPOHP	0.9998	−3.5	4.3	−11	6.7	−3.3	5.3	−0.56	2.9	−7.3	4.4	−1.4	3.1	100	1.2	97	4.0	98	5.0	22	0.006
28	mPHHP	0.9989	0.05	3.3	−9.1	8.3	−3.2	4.9	2.2	2.1	−5.6	3.0	−1.0	2.2	102	1.3	96	4.5	94	2.6	22	0.014
29	mCOCH	0.9984	−3.5	4.5	−12	5.1	1.0	4.4	−1.2	3.8	−7.0	4.3	3.5	2.2	94	2.0	96	7.9	96	7.3	24	0.008
30	mPCHP	0.9990	−1.9	4.2	−13	4.7	−3.4	5.4	−0.19	3.7	−8.4	5.3	−0.91	3.1	95	3.8	97	2.4	98	3.9	25	0.012
31	mETP	0.9992	−2.2	6.5	−10	9.2	0.15	5.9	2.3	3.2	−7.4	3.3	2.6	4.5	109	2.5	105	2.6	102	1.3	31	0.006
32	mTBTP	0.9982	−1.6	7.0	−12	9.2	−0.09	3.1	1.0	7.0	−9.0	5.1	−1.1	3.0	90	9.0	96	2.2	98	0.73	30	0.026
33	mBzTP	0.9846	−3.4	3.8	−10	9.6	−5.0	4.3	−1.5	3.7	−6.9	4.7	−3.3	2.4	109	5.5	109	3.1	117	1.4	30	1.0
34	TEP	0.9973	−3.3	5.0	5.2	3.2	−2.5	4.4	−4.5	4.8	4.9	3.6	−2.3	3.4	106	5.3	109	2.6	102	1.0	−88	0.028
35-1	TNBP	0.9953	2.0	2.8	3.3	2.5	−0.63	3.0	0.89	2.2	3.1	1.6	−2.2	2.0	96	0.44	94	2.2	88	1.7	−56	0.016
35-2	TIBP	0.9953	2.0	2.8	3.3	2.5	−0.63	3.0	0.89	2.2	3.1	1.6	−2.2	2.0	96	0.44	94	2.2	88	1.7	−56	0.016
37	TCEP	0.9995	−4.8	6.1	2.1	4.5	−6.2	5.1	−4.1	6.0	0.82	3.6	−5.4	4.1	97	8.3	104	3.4	102	2.0	−18	0.028
38	TPP	0.9979	1.0	2.3	−0.34	3.0	−0.61	3.0	−0.32	2.0	−1.4	2.7	−2.4	0.90	109	2.5	105	4.7	99	6.8	−6	0.016
39	TPhP	0.9664	−0.55	3.3	1.1	2.6	−1.0	2.4	1.3	2.4	0.38	1.6	−1.4	2.4	95	3.8	81	2.2	93	1.1	−42	0.074
40	TBOEP	0.9978	4.3	3.5	2.1	2.5	−0.12	3.0	3.1	3.3	2.0	1.8	−2.0	0.90	96	3.7	92	2.0	97	9.4	−63	0.036
41-1	DNBP	0.9998	−4.6	3.0	−6.30	5.6	−3.2	4.3	−3.5	1.1	−3.9	2.4	−1.4	2.4	101	1.8	99	6.5	97	3.7	23	0.030
41-2	DIBP	0.9998	−4.6	3.0	−6.30	5.6	−3.2	4.3	−3.5	1.1	−3.9	2.4	−1.4	2.4	101	1.8	99	6.5	97	3.7	23	0.030
43	DPhP	0.9980	−3.2	2.8	−7.7	6.9	−2.1	3.8	−1.8	0.90	−4.7	2.4	−0.52	2.0	98	3.9	101	0.70	102	9.7	−2	0.028
44	BMPP	0.9990	3.7	4.4	−2.0	3.7	5.6	5.3	0.93	3.5	−3.7	1.8	3.9	4.8	103	2.7	94	8.3	94	6.3	11	0.050
45	BDCIPP	0.9997	8.9	8.6	−3.0	2.3	−0.29	2.6	4.4	2.8	−2.3	1.8	−0.38	2.7	97	5.2	103	0.69	103	5.5	20	0.200
46	MeP	0.9957	3.1	5.4	−1.6	2.0	−0.06	0.90	0.78	4.6	−2.3	1.8	0.28	0.70	84	3.7	88	6.1	91	6.9	41	0.048
47	EtP	0.9964	0.78	7.2	−0.86	1.6	−0.44	2.3	0.41	7.4	−1.5	0.70	−0.94	2.1	95	1.2	96	3.6	96	9.1	37	0.040
48	PrP	0.9969	−0.64	8.9	−1.5	1.9	−2.6	1.6	0.04	9.0	−2.4	1.2	−2.8	1.8	99	0.93	95	4.6	99	6.4	37	0.010
49	BuP	0.9920	0.97	3.4	1.4	1.3	−0.94	1.3	−0.64	3.3	1.1	0.60	−0.86	1.3	80	2.6	95	3.2	100	6.0	30	0.016
50	BzP	0.9989	5.8	3.7	−1.1	1.6	−1.1	1.3	4.5	3.6	−0.93	1.8	−1.1	1.3	97	2.1	97	4.1	100	6.4	27	0.010
51	HeP	0.9983	−6.3	8.6	−0.96	3.0	0.19	1.1	−2.5	4.6	−1.2	3.0	0.43	0.80	72	3.6	84	2.0	89	4.7	−31	0.010
52	BP-1	0.9991	3.4	7.5	3.2	2.4	−3.2	3.8	1.4	7.7	3.3	2.3	−3.2	4.2	107	1.9	93	3.8	95	5.9	27	0.028
53	BP-2	0.9987	−4.7	4.7	1.6	1.5	−0.75	1.8	−2.6	4.4	1.4	1.6	−0.71	2.0	107	3.4	86	5.7	85	8.3	40	0.012
54	BP-3	0.9986	−9.3	8.8	−0.53	4.9	−3.3	1.8	−4.2	4.9	1.7	2.8	−3.2	1.7	96	1.6	92	2.0	96	3.7	−56	0.010
55	BP-6	0.9857	0.10	2.9	1.1	2.5	−1.3	1.8	1.6	2.0	2.4	1.8	−1.4	1.8	88	1.5	100	5.9	104	4.7	−53	0.028
56	BP-8	0.9994	6.79	4.5	−0.09	3.1	−0.11	1.6	7.5	4.5	1.2	2.2	−0.10	1.7	101	3.2	98	4.0	95	5.4	−4	0.012
57	4-OH-BP	0.9929	−0.75	3.1	−0.85	2.6	−0.45	1.7	−2.0	2.3	−2.2	1.5	−1.2	1.2	106	1.3	100	2.1	96	2.2	34	0.026
58	BPA	0.9953	0.79	5.8	1.4	4.8	−0.45	2.0	−1.3	2.6	−0.89	3.4	−0.34	2.2	85	6.4	94	9.1	94	7.3	48	0.124
59	BPF	0.9943	2.2	9.7	0.30	1.8	1.1	3.0	8.6	5.6	−0.07	1.6	−0.04	2.6	112	5.7	94	1.6	97	5.8	51	0.120
60	BPS	0.9935	−4.2	4.4	1.0	2.0	−2.5	2.7	−3.3	4.0	1.5	1.9	−3.4	2.1	81	8.2	96	0.74	99	4.6	49	0.008
61	BPB	0.9533	−8.5	6.5	−2.3	2.6	0.59	2.6	−1.6	6.8	−1.5	2.2	−0.37	2.0	119	4.3	88	2.6	89	2.9	42	0.112
62	BPZ	0.9947	−4.2	8.2	−0.14	4.0	−2.5	2.0	0.87	4.7	2.3	1.3	−1.8	0.80	103	6.2	95	6.3	97	6.2	38	0.102
63	BPAP	0.9945	−8.2	9.8	2.2	2.3	−1.5	2.0	−2.4	7.0	3.1	1.7	−1.1	1.3	98	3.1	97	5.6	91	7.7	35	0.080
64	BPAF	0.9996	−2.6	4.9	0.33	1.8	−1.2	1.6	−0.05	3.0	0.36	2.0	−1.8	1.2	105	3.3	93	2.6	90	5.9	33	0.054
65	BPP	0.9745	−8.1	10	−0.76	4.8	−1.4	1.6	−0.27	9.4	1.3	3.7	−1.2	1.1	88	0.32	84	5.2	90	6.7	−77	0.142
66-1	2,4,5-TCP	0.9968	0.56	6.5	−4.8	8.1	4.8	6.6	2.3	5.7	−6.8	7.3	1.8	4.5	103	4.1	101	1.4	95	6.2	29	0.020
66-2	2,4,6-TCP	0.9968	0.56	6.5	−4.8	8.1	4.8	6.6	2.3	5.7	−6.8	7.3	1.8	4.5	103	4.1	101	1.4	95	6.2	29	0.020
68	2,3,5,6-TeCP	0.9961	1.6	4.4	2.6	2.8	−0.69	0.50	1.5	4.1	3.0	2.2	−0.53	0.40	96	2.5	106	3.1	94	5.6	22	0.046
69	2,3,4,6-TeCP	0.9942	−2.7	5.0	1.5	3.0	1.5	1.8	−2.8	5.3	1.7	3.0	1.6	2.0	106	6.3	94	5.1	97	1.6	−10	0.044
70	2,3,4,5-TeCP	0.9937	−0.43	4.2	2.2	2.7	−1.3	1.9	−1.0	4.5	2.5	2.6	−1.4	2.0	104	4.0	91	1.7	104	8.8	−21	0.014
71	PCP	0.9978	6.9	5.6	−0.63	2.7	−1.7	1.3	4.9	4.7	−0.36	2.9	−1.8	1.3	109	5.8	97	0.66	95	5.9	10	0.026
72	TCC	0.9966	−6.4	6.2	−2.4	4.7	−2.2	2.2	−3.9	4.7	−2.5	3.6	−2.0	2.2	85	0.25	84	1.4	87	3.2	−98	0.034
73	TCS	0.9935	−5.8	4.7	−1.7	4.2	−0.97	1.9	−6.5	2.8	−1.7	4.1	−0.49	1.5	109	3.8	108	5.5	101	4.9	−49	0.052
74	TCBPA	0.9912	1.1	4.9	−3.3	3.5	−4.4	2.1	2.9	4.2	−4.4	3.5	−4.9	1.4	109	6.7	104	2.6	103	7.2	14	0.080
75	TeCBPA	0.9875	3.9	9.8	−5.0	5.7	−1.3	3.9	−1.4	4.3	−4.4	3.2	−3.2	2.7	112	5.7	105	6.3	98	5.9	23	0.072
76	TBBPA	0.9964	−0.95	6.3	0.15	4.0	0.28	2.9	−2.7	6.6	6.7	5.8	−1.2	2.0	98	7.9	96	2.0	103	4.3	17	0.034
77	BADGE	0.9979	−2.7	6.7	3.0	2.7	−1.3	2.6	−4.2	6.3	2.3	2.1	−1.9	2.1	93	2.1	88	7.8	93	1.9	−5	0.400
78	BADGE·H₂O	0.9568	−7.0	6.7	1.1	1.8	−1.6	2.4	−9.1	4.5	0.96	1.8	−1.0	1.9	118	1.1	78	7.0	81	3.4	34	0.322
79	BADGE·2H₂O	0.9690	1.4	6.1	1.2	3.3	2.6	3.5	0.29	6.8	1.0	2.4	1.8	2.8	128	9.4	62	0.72	68	6.8	42	0.146
80	1-Nap	0.9909	3.8	8.0	2.6	2.2	−1.2	3.0	−1.5	5.4	2.0	1.8	−1.5	2.4	86	4.6	94	2.4	97	2.5	60	0.080
81	2-Nap	0.9967	6.2	7.5	−0.92	1.7	−2.0	1.2	6.9	7.7	−0.17	1.4	−2.1	1.2	75	5.0	92	2.3	97	4.0	34	0.050
82-1	2-Fluo	0.9996	0.29	7.9	1.2	1.8	1.3	1.3	−3.3	5.5	1.5	1.8	1.6	1.3	103	7.8	90	7.8	96	5.5	24	0.026
82-2	3-Fluo
82-3	9-Fluo
85-1	2-Phen	0.9986	−4.0	6.7	1.1	3.1	0.42	1.3	−1.7	7.4	2.0	2.9	−0.17	0.90	97	2.3	91	2.8	90	3.5	26	0.020
85–2	3-Phen	0.9986	−4.0	6.7	1.1	3.1	0.42	1.3	−1.7	7.4	2.0	2.9	−0.17	0.90	97	2.3	91	2.8	90	3.5	26	0.020
87–1	1-Phen	0.9987	4.2	8.4	3.2	4.7	−0.95	2.6	−1.9	3.7	4.6	3.2	−2.3	1.6	112	8.8	96	3.6	103	3.1	23	0.020
87–2	9-Phen	0.9987	4.2	8.4	3.2	4.7	−0.95	2.6	−1.9	3.7	4.6	3.2	−2.3	1.6	112	8.8	96	3.6	103	3.1	23	0.020
89	4-Phen	0.9995	3.2	7.0	3.3	2.9	1.1	1.7	0.75	6.2	2.6	2.4	1.2	1.7	103	1.9	92	2.2	92	4.6	18	0.030
90	1-Pyr	0.9991	0.56	4.7	9.7	10	6.1	10	−0.50	4.9	11	7.4	1.8	7.6	106	6.3	103	2.5	97	4.7	17	0.020
91	nitenpyram	0.9993	−2.3	5.9	6.8	3.8	1.1	6.0	−2.8	6.2	5.3	2.4	−0.74	4.6	111	0.64	101	6.3	95	6.3	60	0.108
92	thiamethoxam	0.9989	9.0	7.6	2.4	3.4	1.8	4.4	6.1	3.4	4.1	2.6	0.49	4.2	106	1.3	90	3.0	104	0.34	21	0.036
93	imidacloprid	0.9986	9.6	5.5	2.7	3.9	0.05	3.2	9.7	4.9	1.1	1.9	−1.1	2.4	95	5.2	94	4.7	93	3.0	38	0.096
94	acetamiprid	0.9995	4.6	4.8	3.2	2.8	0.56	4.1	4.2	4.4	2.4	1.8	−1.1	2.9	108	0.66	96	0.52	94	6.7	38	0.032
95	thiacloprid	0.9995	0.88	1.7	0.79	1.4	1.4	2.8	0.69	1.4	0.53	1.4	−0.17	1.5	106	1.3	95	4.3	98	2.5	37	0.068
96	clothianidin	0.9989	−6.0	4.1	6.3	3.2	0.19	5.7	−7.0	4.2	5.3	2.1	−3.2	1.8	105	2.0	91	2.0	105	2.3	61	0.026
97	flonicamid	0.9973	3.3	6.2	−2.4	8.0	−0.89	7.6	1.4	6.7	−3.4	8.5	0.99	7.7	156	5.3	107	4.6	88	4.4	63	0.200
98	N-Dmt	0.9920	1.1	4.7	2.9	4.4	3.1	7.4	−1.7	2.1	0.77	2.5	0.08	6.6	138	5.8	102	1.3	91	8.1	31	0.024
99	N-Dma	0.9996	0.82	3.7	−0.12	3.3	2.8	4.1	−0.85	3.0	−1.2	2.7	1.0	1.7	114	8.6	100	9.2	99	3.9	63	0.060
100	Ta	0.9995	−0.07	3.9	2.4	2.6	4.5	6.2	−2.8	2.7	1.8	2.2	1.7	4.2	106	2.6	99	5.1	96	1.6	59	0.010
101	imidaclothiz	0.9976	7.8	4.4	6.0	3.4	2.7	3.8	5.3	2.7	7.3	2.9	1.9	1.6	95	2.1	104	4.7	91	11	37	0.048
102	6-Cn	0.9991	−6.8	5.9	−12	6.4	−1.9	4.8	−4.1	3.4	−8.3	4.4	0.29	2.1	103	6.9	95	1.6	100	3.1	31	0.046
103	sulfoxaflor	0.9998	−0.09	6.6	2.1	2.5	−0.40	2.0	0.05	5.0	2.1	2.6	0.12	1.4	106	1.3	95	8.7	98	4.3	42	0.008
104	4-nitrophenol	0.9992	0.15	7.6	1.4	3.2	1.8	1.8	5.6	3.5	0.54	2.6	0.96	1.2	98	6.7	100	6.7	94	2.6	37	0.176
105	2,4-D	0.9995	8.4	3.9	1.0	2.1	−4.0	4.9	7.1	3.3	0.50	2.2	−6.7	2.4	109	0.6	100	4.1	94	1.5	38	0.058
106	TCPY	0.9974	−4.2	5.1	−3.3	6.3	−2.1	2.4	−1.4	2.0	0.05	2.7	−3.0	1.7	107	3.3	102	1.3	97	8.7	30	0.094
107	trans-DCCA	0.9990	−2.3	5.3	1.3	4.3	−0.69	2.9	−1.9	3.6	−2.0	4.2	0.98	1.9	102	1.3	103	2.0	100	0.71	23	0.166
108	cis-DCCA	0.9617	−2.5	7.1	−8.2	8.9	−3.3	5.0	0.82	5.1	−4.6	4.7	−1.2	2.2	98	0.72	93	4.2	96	5.8	30	0.100
109	3-PBA	0.9992	−4.2	5.1	−12	6.4	−4.1	4.9	−1.9	2.8	−8.0	5.6	−2.1	1.9	98	0.72	93	4.2	96	5.8	31	0.036
110	4F-3PBA	0.9990	−3.2	4.1	−13	3.7	−4.0	4.9	−1.1	2.2	−9.4	5.4	−1.8	2.6	102	1.3	94	5.4	97	6.1	29	0.008
111	2,4,5-T	0.9950	−7.5	3.8	−9.8	8.3	−3.0	4.1	−7.0	2.7	−6.9	3.6	−1.4	1.7	111	6.3	100	1.0	100	11	33	0.018
112	pyrimethanil	0.9992	1.7	3.2	2.4	1.9	1.3	3.5	2.4	3.1	1.8	1.6	−0.73	1.4	107	4.6	94	3.2	101	6.3	−4	0.058
113	dinotefuran	0.9998	−12	11	3.9	3.8	−0.45	5.8	−7.4	10	4.0	2.9	−1.7	4.8	100	3.0	100	0.92	90	9.4	34	0.010
114	metribuzin	0.9690	−12	9.5	2.4	4.7	0.44	5.3	−13	9.0	2.7	4.7	−0.95	4.2	97	3.4	94	6.5	103	6.3	36	0.100
115	atrazine	0.9989	5.8	3.1	2.9	2.7	3.0	2.9	4.9	2.9	2.3	2.2	1.6	2.4	127	0.38	122	4.6	117	1.9	14	0.128
116	cyprodinil	0.9994	4.6	5.2	3.6	3.8	−0.97	3.0	3.6	3.9	2.4	1.2	−2.4	2.1	110	5.8	91	2.7	96	3.7	−82	0.034
117	metalaxyl	0.9994	3.8	2.8	1.4	1.6	0.36	2.5	4.0	1.7	1.3	1.4	−1.0	1.2	107	1.3	99	2.2	99	6.4	22	0.032
118	tebuconazole	0.9992	−1.1	3.9	4.6	2.8	−1.8	2.5	−2.7	4.0	3.5	1.7	−2.7	2.4	94	10	92	5.9	97	9.1	10	0.052
119	propiconazole	0.9743	2.8	2.1	1.0	3.7	−2.3	3.2	1.9	1.8	−0.40	2.1	−4.0	1.7	107	2.7	77	4.0	83	2.1	−12	0.012
120	tetraconazole	0.9991	3.9	6.0	1.2	2.7	−1.2	3.2	5.5	5.1	0.27	2.2	−2.8	2.2	112	7.1	106	6.0	102	9.0	8	0.072
121	azoxystrobin	0.9998	1.6	2.7	1.7	2.6	1.6	2.4	0.75	2.7	1.0	2.0	0.51	1.6	104	4.7	97	2.5	98	6.1	17	0.080

RE: relative error; RSD: relative standard deviation; ME: matrix effect; LOD: limit of detection; There is no chromatographic resolution between compounds with same ID; therefore, sum concentrations are expressed for these isomers by using the present developed method.