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. Author manuscript; available in PMC: 2021 May 11.
Published in final edited form as: Inorg Chem. 2020 Mar 27;59(7):5116–5132. doi: 10.1021/acs.inorgchem.0c00372

Table 4.

Photophysical Properties of the Eu3+ and Tb3+ Complexes Formed with OxyMepa and Oxyaapa (pH = 7.4 in 0.1 M MOPS, 22 °C)a

λmax/nm ε(λmax)/(M−1 cm−1) QY/% τ(H2O)/ms τ(D2O)/ms q
Eu-OxyMepa 273 10300 0.36(1) 0.390(1) 1.671(4) 1.8
Tb-OxyMepa 273 10300 1.4(1) 1.231(4) 2.558(6) 1.8
Eu-Oxyaapa 273 10300 0.86(4) 1.145(4) 1.635(3) −0.1
Tb-Oxyaapa 273 10200 2.1(2) 1.818(3) 1.905(4) −0.2
a

The values in the parentheses are one standard deviation of the last significant figure.