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. 2021 May 11;11:9960. doi: 10.1038/s41598-021-88929-7

Table 4.

Sorption isotherms and their non-linear and linear forms with corresponding plots.

Isotherm Non linear Linear Parameters Plot
Freundlich qe=KFCe1/n logqe=logKF+1nlogCe

KF (mg g−1): sorption capacity

1/n: intensity of sorption

Ce (mg L−1): equilibrium concentration

qe (mgg−1): sorption capacity

logqe vs logCe
Langmuir qe=QmaxKLCe1+KLCe

Ceqe=1QmaxKL+CeQmax

RL=11+KLCo

Qmax (mg g−1): maximum monolayer sorption capacity

KL (L mg−1): constant related with sorption energy

RL: separation factor

Co (mg L−1): Initial concentration

Ceqe vs Ce
Temkin qe=RTbTlnKTCe qe=RTlnKT+RTbTlnCe

bT (J mol−1): constant related with heat of sorption

KT (L g−1): Temkin isotherm constant

qe vs lnCe
D-R qe=qdexp-βε2

lnqe=lnqd-βε2

ε=RTln1+1Ce

E=12β

β (mol2/kJ2): constant related with free energy

qd (mg g−1): maximum sorption capacity

ε: Polanyi potential

R (Jmol−1 K−1): gas constant

T (K): temperature

E (kJ mol−1): mean sorption energy

lnqe vs ε2