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. Author manuscript; available in PMC: 2021 May 12.
Published in final edited form as: Inorg Chem. 2017 May 16;56(11):6609–6623. doi: 10.1021/acs.inorgchem.7b00710

Table 5.

Electrochemical Properties of [Co(BTSC)(L)2]+ Complexesa

Compound E1/2,Co(II/I) Epc, Co(III/II)
[Co(ATS)(NH3)2]+ −1.18 −1.10
[Co(ATS)(Im)2]+ −1.19 −0.86
[Co(ATS)(BnA)2]+ −1.18 −0.83
[Co(PTS)(NH3)2]+ –1.11 –0.92
[Co(PTS)(Im)2]+ –1.12 –0.84
[Co(PTS)(BnA)2]+ –1.14 –0.84
[Co(GTS)(NH3)2]+ –1.02 –0.95
[Co(GTS)(Im)2]+ –1.00 –0.72
[Co(GTS)(BnA)2]+ –1.00 –0.69
a

Potentials are referenced to the SCE. Data were obtained at a glassy carbon working electrode in anhydrous DMF containing 0.10 M TBAP, using a scan rate of 100 mV/s at 25 °C.