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. Author manuscript; available in PMC: 2021 May 12.
Published in final edited form as: Synlett. 2019 Nov 27;31(2):102–116. doi: 10.1055/s-0039-1691501

Scheme 16.

Scheme 16

Du Bois, Burns, and Zare propose that sulfamate esters direct bromination based on a radical chain propagation mechanism (A), and use mass spectrometry and a crossover experiment (B) to support this claim.