Fig. 3. Section of the solid-state structure of [NPr3Me][Cl7] showing one anion and two cations [one at (x, y, z) and one at (−x, 1 − y, 1 − z)]. Displacement ellipsoids are shown at the 50% probability level. Color code: green = chlorine, blue = nitrogen, grey = carbon, white = hydrogen. Selected bond lengths [pm] and angles [°]: Cl1–Cl2 277.08(8), Cl1–Cl4 275.97(6), Cl1–Cl6 277.36(6), Cl2–Cl3 203.80(8), Cl4–Cl5 203.28(7), Cl6–Cl7 202.66(8), Cl2–Cl1–Cl6 82.41(2), Cl4–Cl1–Cl2 93.69(2), Cl4–Cl1–Cl6 140.25(2), Cl2–Cl1–Cl4–Cl6 82.55(4), Cl⋯H in the range 2.77 to 2.90.
