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. Author manuscript; available in PMC: 2021 May 15.
Published in final edited form as: ACS Catal. 2020 Apr 24;10(10):5657–5662. doi: 10.1021/acscatal.0c01310

Table 4.

Scope of Aliphatic Acids for γ-C(sp3)–H Acyloxylation of Free Aminesa,b

graphic file with name nihms-1645590-t0005.jpg
a

Experiments were performed with substrate 1a (0.10 mmol), Pd(OAc)2 (0.01 mmol), TDG (0.075 mmol), N-fluoro 2,4,6-methylpyridinium tetrafluoroborate (0.20 mmol), HFIP (0.5 mL), 70 °C, 16 h.

b

Isolated yields.

c

Reaction performed with 0.5 eq of TDG.

d

Reaction performed with 2.0 eq of acid.

e

Reaction performed with 1.0 eq of TDG.