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. 2021 Apr 26;26(9):2528. doi: 10.3390/molecules26092528

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© 2021 by the author.

Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).

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Equilibrium concentrations of glutathionyl-hemoglobin (HbSSG%) calculated according to the Nernst equation. The E_h redox potentials correspond to those of the GSSG/GSH redox couple calculated according to the concentrations of GSH and GSSG measured during the experiment. Different estimates of E₀ for the HbS/HbSH couple are used to derive the concentration ratio dependent term of the Nernst equation for HbSSG/HbSH. For clarity, only two values for higher and two for lower E₀ of the HbS/HbSH couple are reported.