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. 2021 May 18;12:2932. doi: 10.1038/s41467-021-23065-4

Fig. 3. In situ sample characterisation under electrocatalytic reaction conditions.

Fig. 3

Cu K-edge XANES spectra and first-order derivatives of the XANES spectra (collected at 200 mA cm−2 under CO2RR conditions) for the sample containing a only CuPc b a 1:1 ratio of CNP to CuPc c a 4:1 ratio of CNP to CuPc. d Fourier-transformed Cu K-edge EXAFS spectra (collected at 200 mA cm−2 under CO2RR conditions) and fitting lines for samples containing different ratios of CNP to CuPc. e Comparison of the metallic Cu–Cu coordination number determined from EXAFS analysis and methanation selectivity.