Preparation of the organozinc halides.
| |||||
|---|---|---|---|---|---|
| Entry | RX | 1 | Time | % conva | Titerb |
| 1 | PhI | 1a | 2 h | 99 | 0.89 M |
| 2 | 4-MeO2CC6H4I | 1b | 2 h | 99 | 0.90 M |
| 3 | c-HexBr | 1c | 22 h | 97 | 0.86 M |
| 4 | n-C8H17Br | 1d | 4 h | 98 | 0.87 M |
| 5 | 4-CF3C6H4I | 1e | 2 h | 99 | 0.95 M |
Apparent conversion determined by GC analysis after hydrolysis of the reaction mixture.
Determined by GC analysis after iodolysis of the reaction mixture.17