Preparation of the organozinc halides.
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Entry | RX | 1 | Time | % conva | Titerb |
1 | PhI | 1a | 2 h | 99 | 0.89 M |
2 | 4-MeO2CC6H4I | 1b | 2 h | 99 | 0.90 M |
3 | c-HexBr | 1c | 22 h | 97 | 0.86 M |
4 | n-C8H17Br | 1d | 4 h | 98 | 0.87 M |
5 | 4-CF3C6H4I | 1e | 2 h | 99 | 0.95 M |
Apparent conversion determined by GC analysis after hydrolysis of the reaction mixture.
Determined by GC analysis after iodolysis of the reaction mixture.17