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Additions to different enones catalysed by L3/Pd(dba)2 [40].
 | |||||
| entry | cyclic substrates | Ar | yield (%) | ee (%) | |
| n | |||||
| 1 | 0 | Ph | 94 | 54 | |
| 2 | 1 | Ph | 92 | 76 | |
| 3 | 1 | 4-Me-C6H4 | 89 | 78 | |
| 4 | 1 | 4-MeO-C6H4 | 83 | 76 | |
| 5 | 1 | 4-t-Bu-C6H4 | 92 | 79 | |
| 6 | 1 | 4-CF3-C6H4 | 81 | 4 | |
| 7 | 1 | 4-F-C6H4 | 45 | 68 | |
| 8 | 1 | 1-naphthyl | 80 | 42 | |
| 9 | 2 | Ph | 90 | 38 | |
| acyclic substrates | |||||
| R1 | R2 | ||||
| 10 | Me | Me | Ph | 53 | 44 |
| 11 | Me | Et | Ph | 62 | 47 |
| 12 | iPr | Me | Ph | 70 | 52 |
| 13 | n-C5H11 | Me | Ph | 99 | 42 |
