Table 12.

Application of dimeric palladacycle PdL6 in the addition reactions of arylboronic acids to various enones [43].

entry	cyclic substrates		Ar	yield (%)	ee (%)
	n
1	0		Ph	64	50 (S)
2	1		Ph	89	92 (R)
3	2		Ph	72	87 (R)
	acyclic substrates
	R1	R2
4	4-F-C6H4	Ph	Ph	88	81
5	4-Cl-C6H4	Ph	Ph	92	78
6	4-Br-C6H4	Ph	Ph	88	78
7	4-MeO-C6H4	Ph	Ph	95	81
8	4-Me-C6H4	Ph	Ph	97	81
9	4-CF3-C6H4	Ph	Ph	92	69
10	2-naphthyl	Ph	Ph	88	85
11	4-Ph-C6H4	Ph	Ph	85	79
12	3,4-(CH2O2)-C6H3	Ph	Ph	95	81
13	Ph	Me	4-Me-C6H4	63	87
14	Me	Me	Ph	56	93
15	Ph	Ph	2-naphthyl	97	77
16	Ph	Ph	4-F-C6H4	92	79
17	Ph	Ph	4-Cl-C6H4	56	82
18	Ph	Ph	4-Br-C6H4	88	56
19	Ph	Ph	4-Me-C6H4	89	69
20	Ph	Ph	4-MeO-C6H4	83	85
21	Ph	Ph	4-CF3-C6H4	47	80