Table 16.

Addition reactions of boronic acids to five and six-membered enones catalysed by in situ-prepared Pd-bisNHC complex PdL8 [46].

entry	n	Ar	yield (%)	ee (%)
1	0	2-Me-C6H4	36	50
2	0	2-MeO-C6H4	35	51
3	0	4-MeO-C6H4	30	35
4	0	1-naphthyl	24	30
5	1	Ph	98	51
6	1	2-Me-C6H4	62	33
7	1	1-naphthyl	48	30