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. 2021 May 10;17:1048–1085. doi: 10.3762/bjoc.17.84

Table 18.

Addition reactions of phenylboronic acid to various 3-substituted enones catalysed by L9/Pd(TFA)2 [47,49].

graphic file with name Beilstein_J_Org_Chem-17-1048-i018.jpg
entry n R yield (%) ee (%)
1 0 Me 84 91
2 2 Me 85 93
3 1 Et 96 92
4 1 n-Bu 95 91
5 1 Bn 74 91
6 1 Cy 86 85
8 1 iPr 86 79
7 1 cyclopropyl 68 88
9 1 (CH2)3OBn 65 91