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. 2021 May 10;17:1048–1085. doi: 10.3762/bjoc.17.84

Table 20.

Addition reactions of arylboronic acids to 3-acetyl-2-cyclohexanone catalysed by L9/Pd(TFA)2 [49].

graphic file with name Beilstein_J_Org_Chem-17-1048-i020.jpg

entry n Ar yield (%) ee (%)

1 1 4-Cl-C6H4 85 96
2 1 4-F-C6H4 92 90
3 1 3-Me-C6H4 66 92
4 1 3-(CF3CONH)-4-Me-C6H3 73 91
5 0 Ph 72 93
6 0 3-Me-C6H4 72 90
7 0 4-F-C6H4 57 92