Table 20.
Addition reactions of arylboronic acids to 3-acetyl-2-cyclohexanone catalysed by L9/Pd(TFA)2 [49].
![]() | ||||
| entry | n | Ar | yield (%) | ee (%) |
| 1 | 1 | 4-Cl-C6H4 | 85 | 96 |
| 2 | 1 | 4-F-C6H4 | 92 | 90 |
| 3 | 1 | 3-Me-C6H4 | 66 | 92 |
| 4 | 1 | 3-(CF3CONH)-4-Me-C6H3 | 73 | 91 |
| 5 | 0 | Ph | 72 | 93 |
| 6 | 0 | 3-Me-C6H4 | 72 | 90 |
| 7 | 0 | 4-F-C6H4 | 57 | 92 |
