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. 2021 May 10;17:1048–1085. doi: 10.3762/bjoc.17.84

Table 32.

Addition reactions of arylboronic acids to 3-methyl-2-cyclohexenone catalysed by L13/Pd(TFA)2 [60].

graphic file with name Beilstein_J_Org_Chem-17-1048-i032.jpg

entry Ar yield (%) ee (%)

1 Ph 88 95
2 4-MeO-C6H4 75 70
3 4-Me-C6H4 72 91
4 1-naphthyl 88 89
5 4-CF3-C6H4 86 96
6 4-F-C6H4 81 95
7 3-Me-C6H4 73 88
8 3-Cl-C6H4 88 99