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Asymmetric addition of arylboronic acids to 2-cyclohexenone catalysed by L3/Pd(dba)2 [39].
 | ||||
| entry | Ar | temp. (°C) | yield (%) | ee (%) |
| 1 | Ph | 80 | 82 | 42 |
| 2 | Ph | 60 | 83 | 46 |
| 3 | Ph | 25 | 79 | 66 |
| 4 | 4-Me-C6H4 | 80 | 88 | 61 |
| 5 | 4-Me-C6H4 | 25 | 90 | 71 |
| 6 | 2-Me-C6H4 | 80 | 93 | 25 |
| 7 | 3-Me-C6H4 | 80 | 63 | 58 |
