Table 3.
Examples of the polyol process to obtain AgNPs with various morphologies.
| [Ag+] | EG | protector | [Ag+]:[Protector] | reaction details (temperature/acid content/time) |
AgNP morphology | ref. | |
| 94 mM | 141 mM | PVP | 1:1.5 | EG/140 °C/0.25 mM HNO3 | 15 h | nanocubes 30 nm |
[142] |
| 94 mM | 147 mM | PVP | 1:1.5 | EG/140 °C/0.025 mM HCl | 30 min | nanowires ≈30 nm (d) ≈100 nm (c) |
[143] |
| 125 mM | 188 mM | PVP | 1:1.5 | EG/160 °C | 30 min | nanocubes ≈80 nm |
[139] |
| 250 mM | 375 mM | PVP | 1:1.5 | EG/160 °C | 45 min | nanocubes ≈175 nm |
[139] |
| 0.5 mM | 0.0625 mM | PVP | 1:0.0625 | PEG/260 °C | 24 h | nanospheres ≈54 nm |
[144] |
| 0.25 M | 0.027 M | PVP | 1:0.108 | EG/120 °C | 30 min | nanospheres ≈27 nm |
[145] |