| Poly (arylene ether sulfone)–PASS-4 |
|
>150 days at RT |
Yes |
[123] |
| Poly (arylene ether sulfone) |
|
>150 days at RT |
No |
[123] |
| Polypropylene |
|
Stable at RT, oxidized at >100 °C |
No |
[124] |
| Kevlar(poly(p-phenylene terephthalamide) |
|
>3 months at RT |
Yes |
[58] |
| Polyaniline |
|
Stable for at least a few weeks at RT |
Yes |
[125] |
| Polyimide V |
|
Stable for at least a few days at RT |
Yes |
[126] |
| Polyimide VI |
|
Stable for at least a few days at RT |
Yes |
[126] |
| Polyimide VIII |
|
Stable for at least a few days at RT |
No |
[126] |
| Polyimide IVa |
|
Stable for at least a few days at RT |
Yes |
[127] |
| Polyethersulfones |
|
A few weeks at RT in CSA (Sulfonated in oleum at 30 °C) |
Yes |
[128,129] |
| Poly(phthalazinones)poly(phthalazinone-ether ketone) (PPEK) |
|
>95 h at RT (sulfonated in oleum at 23 °C) |
Yes |
[130] |
| Poly(phthalazinone ether sulfone) (PPES) |
|
Half-life to sulfonation ~50 h at 25 °C |
Yes |
[130] |
| Polyarylhydrazides |
|
A few weeks at RT |
Yes |
[131] |
| Polyarylhydrazides |
|
Rapidly hydrolyzed |
N/A |
[132] |
| Poly-Schiff’s bases |
|
A few weeks at RT |
Slightly soluble |
[133] |
| Poly-Schiff’s bases |
|
A few weeks at RT |
Yes |
[133] |
| Silicon polyamide |
|
Stable (gave red solutions, suggesting ring protonation, i.e., long-term liability to reaction) |
Yes |
[134] |
|
|
|
Stable (gave red solutions, suggesting ring protonation, i.e., long-term liability to reaction) |
Yes |
[134] |
| Nylon 6 (e-caprolactam polymer)(also Nylon 2, 12) |
|
At least a few days at RT (viscosity is measured in 96% H2SO4) |
Yes |
[56,57] |
|
|
|
At least a few days at RT |
Yes |
[59] |
|
|
|
At least a few days at RT |
No |
[59] |
| Quinoxaline ladder polymers |
|
At least a few days at RT |
No |
[135] |
| Polyglycine |
|
Limited hydrolysis on hour timescale in cold H2SO4
|
N/A |
[54,55] |
| PEEK |
|
50% sulfonated in 96.3% sulfuric acid at 22 °C after hours |
Yes |
[53] |
| Polystyrene |
|
Fully sulfonated in minutes at 90 °C, 50% after 10 h at 70 °C, implies stable at RT. |
Unknown |
[136] |
| Polystyrene sulfonate |
|
Stable for >100 h at 90 °C |
Yes |
[136] |