Kinetic and thermodynamic data.
ox | log k exp(M−1 s−1) | ΔG0rxn (eV) | log Keq | E 0(V vs. FeCp+/02) | ΔG0ET (eV) |
---|---|---|---|---|---|
N(ArBr)3 | 7.2 × 105 | −1.15 | 19.7 | 0.67 | −1.43 |
N(ArOMe) (ArBr)2 | 5.4 × 104 | −0.96 | 16.4 | 0.48 | −1.24 |
N(ArOMe)2 (ArBr) | 1.9 × 104 | −0.80 | 13.7 | 0.32 | −1.08 |
N(ArOMe)3 | 9.5 × 103 | −0.64 | 10.9 | 0.16 | −0.92 |
FeCp2+ | 1.9 × 103 | −0.48 | 8.2 | 0.00 | −0.76 |
FeCp*Cp2+ | 3.8 × 102 | −0.21 | 3.6 | −0.27 | −0.49 |
FeCp*2+ | 2.3 × 101 | 0.00 | 0.0 | −0.48 | −0.28 |