Skip to main content
. 2019 Nov 29;11(4):1006–1010. doi: 10.1039/c9sc05147c

Kinetic and thermodynamic data.

ox log k exp(M−1 s−1) ΔG0rxn (eV) log Keq E 0(V vs. FeCp+/02) ΔG0ET (eV)
N(ArBr)3 7.2 × 105 −1.15 19.7 0.67 −1.43
N(ArOMe) (ArBr)2 5.4 × 104 −0.96 16.4 0.48 −1.24
N(ArOMe)2 (ArBr) 1.9 × 104 −0.80 13.7 0.32 −1.08
N(ArOMe)3 9.5 × 103 −0.64 10.9 0.16 −0.92
FeCp2+ 1.9 × 103 −0.48 8.2 0.00 −0.76
FeCp*Cp2+ 3.8 × 102 −0.21 3.6 −0.27 −0.49
FeCp*2+ 2.3 × 101 0.00 0.0 −0.48 −0.28