Binding constants (K, M−1)a,b between cages 1–2 and selected cations in dichloromethane.
Na+ | Cs+ | |||
---|---|---|---|---|
K 11 | K 12 | K 11 | K 12 | |
1a | 6 × 108 | 3 × 106 | 1 × 107 | — |
1b | 4 × 109 | 2 × 106 | 2 × 108 | — |
2a | 1 × 1011 | 2 × 108 | 4 × 109 | 3.3 × 106 |
2b | 9 × 1012 | 1 × 109 | 2 × 107 | c |
Estimated errors: ±15%.
Host : guest stoichiometry is (1 : 1) or (1 : 2).
<3 × 106.