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. 2020 Jan 15;11(6):1478–1484. doi: 10.1039/c9sc05354a

Binding constants (K, M−1)a,b between cages 12 and selected cations in dichloromethane.

Na+ Cs+
K 11 K 12 K 11 K 12
1a 6 × 108 3 × 106 1 × 107
1b 4 × 109 2 × 106 2 × 108
2a 1 × 1011 2 × 108 4 × 109 3.3 × 106
2b 9 × 1012 1 × 109 2 × 107 c
a

Estimated errors: ±15%.

b

Host : guest stoichiometry is (1 : 1) or (1 : 2).

c

<3 × 106.