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The alkaline hydrolysis of various cyclic and open-chain phosphinates.
| Starting Phosphinate | Solvent | Rate Constant, 1 mole−1 s−1 × 104 | ||
|---|---|---|---|---|
| 50 °C | 60 °C | 70 °C | ||
|
50% alcohol–water | 1.18 | 2.24 | 4.22 |
|
80% alcohol–water | 0.300 | 0.568 | 1.08 |
|
50% alcohol–water | 0.730 | 1.39 | 2.63 |
