Photophysical properties of the synthesized compounds.
Compounds | λ abs a [nm] | ε × 10−3a [M−1 cm−1] | λ em a [nm] | Stokes shift [nm] | Φ f b (%) | Φ Δ c |
---|---|---|---|---|---|---|
BODIPY d | 502 | 120.00 | 508 | 6 | 70.0 | ≈0 |
PY-BOD | 568 | 107.09 | 585 | 17 | 9.82 | 0.52 |
PH-BOD | 564 | 111.60 | 576 | 12 | 18.83 | 0.69 |
MeO-BOD | 564 | 115.78 | 579 | 15 | 17.11 | 0.85 |
DMA-BOD | 562 | 96.99 | 577 | 15 | 2.50 | 0.04 |
In toluene (5.0 × 10−6 M).
Fluorescence quantum yield estimated relative to rhodamine 101 as the standard (Φf = 1.0 in methanol).
Singlet oxygen quantum yield was determined with respect to rose bengal (ΦΔ (RB) = 0.54 in ACN).
Literature value.19