Reaction scope II: α-keto-β,γ-unsaturated ester Michael acceptorsa.
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dr determined by 1H NMR spectroscopic analysis of the crude reaction product mixture, with values rounded to nearest 5; er determined by chiral stationary phase HPLC analysis.
CH2Cl2 used as solvent due to low solubility of α-keto-β,γ-unsaturated ester in MeCN.