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. 2021 May 7;12(20):6844–6878. doi: 10.1039/d1sc01711j

Summary of physical and chemical properties and device performances for polymers P1–P191.

Polymers UV-vis λsolmax/λfilmmax (nm) HOMO/LUMOa (eV) Band Gap (eV) Eoptg/Eecg μ h/μe (cm2 V−1 s−1) Max PCE (%) Device configuration OFET (OSCs) Ref.
P1 — −5.17/−3.61 1.40/1.56 0.04/0.01 4.70 BGBC 26
P2 838/857 −5.07/— — 3.10/— — TGBC 27
P3 — — — 2.1(26.2b)/— — BGBC 28
P4 —/789 −5.40/−3.80 1.41/1.60 — 3.80(5.00b) (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 29
P5 —/767 −5.50/−3.80 1.35/1.70 — 3.00(4.10b) (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 29
P6 — — 1.59/1.66 3 × 10−3/7 × 10−3 3.70 BGBC 30
P7 782/782 −5.36/— 1.37/— 3.56/— — BGTC 31
P8 —/796 −5.19/−3.63 1.56/— — 4.56 (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 32
P9 827/882 −5.20/−4.02 1.18/— 0.10/0.10 — BGBC 33
P10 823/864 −5.10/−3.92 1.21/— 0.26/0.05 — BGBC 33
P11 790/836 −5.30/−3.97 1.33/— 0.95(1.51b)/— — BGTC 34
P12 539/563 −5.47/−3.74 1.70/1.73 — 1.51 (ITO/polymer:PCBM/Al) 35
P13 664/684 −5.77/−3.86 1.71/1.91 — 4.90 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 36
P14 654/672 −5.75/−4.03 1.72/— 0.58/2.22 — TGBC 38
P15 713/— −5.89/−4.03 1.86/— —/1.67 — TGBC 39
P16 — −5.63/−4.00 1.44/1.63 6 × 10−3/0.13 2.90 TGBC (ITO/ZnO/PDPP5T:polymer/MoO3/Ag) 40
P17 — −4.78/−3.11 1.28/1.67 — 5.60 (ITO/MoO3/active layer/LiF/Al) 41
P18 770/702 −5.73/−3.66 1.42/2.07 0.77/0.497 — TGBC 42
P19 770/776 −5.80/−3.72 1.39/2.08 1.46/1.14 — TGBC 42
P20 770/702 −5.81/−3.72 1.41/2.09 0.489/0.202 — TGBC 42
P21 812/746 −5.06/−3.68 1.37/— 1.95/0.03 5.40 TGBC (ITO/PEDOT/polymer:PCBM/LiF/Al) 43
P22 711/— — — —/0.1 2.72 TGBC 44
P23 — −5.42/−3.68 1.74/— 0.5/0.72 — TGBC 45
P24 — −5.64/−3.84 1.80/— 0.21/6.04 — TGBC 45
P25 — −4.80/−3.49 1.36/1.31 5.87/— 6.10 BGBC 46
P26 — −4.80/−3.49 1.34/1.31 12.5/— 6.50 BGBC 46
P27 780/785 −5.48/−4.03 1.45/— 3.05/— 5.90 BGBC (ITO/ZnO/polymer:PCBM/MoO3/Ag) 47
P28 774/774 −5.36/−3.93 1.43/— 0.32/— 5.70 BGBC (ITO/ZnO/polymer:PCBM/MoO3/Ag) 47
P29 — −5.28/−3.55 1.53/1.73 0.18/0.48 5.48 TGBC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 48
P30 — −5.14/−3.50 1.54/1.64 0.55/0.08 7.56 TGBC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 48
P31 — −4.73/−3.24 1.49/— 1.20/0.40 5.59 TGBC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 49
P32 — −5.09/−3.63 1.46/— 1.68/0.14 6.96 TGBC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 49
P33 — −5.29/−3.83 1.46/— 1.50/0.35 5.62 TGBC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 49
P34 831/833 −5.24/−3.91 1.17/1.33 0.074/0.053 — TGBC 50
P35 832/833 −5.29/−3.85 1.18/1.44 0.48/0.12 — TGBC 50
P36 832/832 −5.27/−3.74 1.19/1.53 1.09/0.25 — TGBC 50
P37 833/833 −5.24/−3.73 1.16/1.51 0.76/0.13 — TGBC 50
P38 796/806 −5.33/−3.79 1.20/1.54 0.86/0.44 — TGBC 50
P39 785/782 −5.29/−4.21 —/1.08 0.021/1.2 × 10−4 — TGBC 50
P40 — −5.06/−3.68 1.44/— 0.12/— — BGBC 51
P41 — −5.16/−3.20 1.49/1.96 — 5.90 (ITO/MoO3/polymer:PCBM/LiF/Al) 59
P42 — −5.19/−3.20 1.49/1.99 — 6.60 (ITO/MoO3/polymer:PCBM/LiF/Al) 59
P43 569/642 −5.51/−3.52 1.59/1.99 0.034/— 5.10 BGTC (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 62
P44 785/825 −5.19/−3.50 1.27/2.09 0.02/0.02 — BGBC 64
P45 524/538 −5.39/−3.35 1.90/2.04 —/1 × 10−3 — BGBC 65
P46 579/579 −5.25/−3.50 1.68/1.75 1 × 10−3/1 × 10−3 — BGBC 65
P47 615/639 −5.68/−3.96 1.69/1.72 0.21/0.18 — TGBC 66
P48 788/806 −5.49/−4.17 1.32/— 0.053/0.021 — BGBC 67
P49 615/678 −5.37/−3.96 1.38/1.41 — — — 68
P50 687/712 −5.66/−4.20 1.33/1.46 0.069/0.667 — BGBC 69
P51 675/703 −5.78/−4.31 1.39/1.47 0.021/0.227 — BGBC 69
P52 —/665 −5.56/−4.08 1.46/1.48 —/0.01 — BGBC 70
P53 834/858 −5.00/−3.70 1.10/1.30 1.24/0.82 — BGBC 72
P54 790/815 −5.00/−3.60 1.20/1.40 1.37/— — BGBC 72
P55 789/798 −5.28/−3.79 1.25/1.49 1.08/2.23 — TGBC 76
P56 628/624 −5.58/−3.87 1.71/— — 7.30 (ITO/ZnO/PEOz/PBFTAZ:polymer/MoO3/Ag) 79
P57 —/645 −5.82/−3.83 1.50/— — 6.30 (ITO/PEDOT:PSS/polymer: PCBM/LiF/Al) 80
P58 703/709 −5.69/−3.82 1.61/1.59 — 10.7 (ITO/ZnO/PEIE/polymer:PCBM/MoO3/Ag) 81
P59 728/729 −5.54/−3.70 1.53/1.84 3.49/2.77 — TGBC 82
P60 686/689 −5.82/−3.83 1.62/1.99 3.94/3.50 — TGBC 82
P61 711/720 −5.66/−3.46 1.54/2.20 5.33/2.06 — TGBC 83
P62 718/720 −5.63/−3.55 1.57/2.08 6.41/6.76 — TGBC 83
P63 726/731 −5.72/−3.64 1.40/2.08 2.75/9.70 — TGBC 83
P64 742/756 −5.67/−3.64 1.50/2.03 7.28/6.43 — BGBC 84
P65 1050/1035 −4.86/−3.73 0.92/1.13 0.16/0.14 — BGBC 85
P66 927/925 −4.84/−3.46 1.04/1.38 0.39/— — BGTC 86
P67 880/868 −4.98/−3.53 1.15/1.45 0.45/— — BGTC 86
P68 730/759 −5.12/−3.49 1.36/1.63 14.4/— — TGBC 87
P69 848/839 −5.13/−3.58 1.21/1.55 3.93/1.07 — TGBC 88
P70 914/926 −4.90/−3.90 1.05/1.00 0.40/0.70 — TGBC 89
P71 897/909 −4.80/−3.70 1.13/1.10 0.20/0.20 — TGBC 89
P72 864/875 −4.80/−3.60 1.19/1.20 0.40/0.10 — TGBC 89
P73 —/665 −5.10/−3.50 1.60/— 0.31/— 9.1 (ITO/ZnO/polymer: PCBM/MoO3/Ag) 90
P74 670/665 −5.15/−3.67 1.48/— — 5.0 (ITO/ZnO/polymer: PCBM/MoOx/Ag) 91
P75 642/640 −5.39/−3.80 1.59/— — 5.6 (ITO/ZnO/polymer: PCBM/MoOx/Ag) 91
P76 660/665 −5.34/−3.86 1.58/— — 5.1 (ITO/ZnO/polymer: PCBM/MoOx/Ag) 91
P77 — −5.07/−3.51 1.56/— — 6.2 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 92
P78 — −5.10/−3.54 1.56/— — 6.92 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 92
P79 729/729 −5.20/−3.67 1.53/— — 9.63 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 92
P80 505/501 — 2.32/— — 5.75 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 93
P81 523/523 — 2.23/— — 6.32 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 93
P82 551/575 — 2.16/— 0.55/— — BGBC 94
P83 505/541 — 2.29/— 6 × 10−3/— — BGBC 94
P84 — −5.42/−3.57 —/1.85 — 11.0 (ITO/PEDOT:PSS/polymer:m-ITIC/PDINO/Al) 96
P85 781/801 −5.54/−3.84 1.37/1.70 8.8 × 10−2/— 3.39 BGTC (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 97
P86 737/773 −5.30/−3.72 1.39/1.58 0.18/— 4.79 BGTC (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 97
P87 673/668 −5.34/−3.62 1.55/1.71 8.95 × 10−4/— 5.03 BGBC (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 99
P88 663/677 −5.77/−3.66 2.03/2.11 — 3.12(5.26b) (ITO/PFN/polymer:PCBM/MoO3/Ag) 100
P89 708/706 −5.24/−3.56 1.44/1.68 4.82/1.11 — TGBC 101
P90 706/703 −5.11/−3.55 1.45/1.56 8.09/0.74 — TGBC 101
P91 594/606 −5.24/−3.72 1.71/1.52 — 3.49(6.41b) (ITO/PEDOT:PSS/polymer:PCBM/LiF/Al) 102
P92 600/606 −5.41/−3.34 1.72/2.07 0.35/— — BGBC 103
P93 600/626 −5.40/−3.62 1.68/1.78 0.037/— — BGBC 103
P94 628/628 −5.25/−3.36 1.63/1.89 0.33/— — BGBC 104
P95 624/630 −5.35/−3.39 1.64/1.96 0.39/— — BGBC 104
P96 624/632 −5.20/−3.36 1.60/1.84 0.30/— — BGBC 104
P97 616/628 −5.27/−3.43 1.63/1.84 0.48/— — BGBC 104
P98 646/648 −5.82/−3.89 1.58/1.93 0.47/— — BGBC 104
P99 632/642 −5.99/−3.93 1.60/2.06 0.31/— — BGBC 104
P100 944/986 −5.33/−3.86 0.95/1.47 0.16/0.14 — BGBC 105
P101 — −5.70/−3.88 1.42/1.82 1.70/1.37 — TGBC 106
P102 1107/1107 −5.18/−3.94 0.71/1.24 0.45/0.22 — TGBC 107
P103 — −5.72/−4.15 1.31/1.67 —/1.74 — TGBC 108
P104 — −5.80/−4.37 1.32/1.43 —/3.22 — TGBC 108
P105 812/876 −5.87/−3.92 1.26/1.95 5.97/7.07 — TGBC 109
P106 838/844 −5.96/−4.32 1.31/1.64 —/1.24 — TGBC 110
P107 806/794 −5.60/−4.06 1.23/1.54 0.10/0.14 — BGBC 111
P108 787/777 −5.76/−3.79 1.45/1.97 0.12/0.14 — BGBC 112
P109 816/806 −5.65/−3.84 1.41/1.81 0.51/0.50 — BGBC 112
P110 844/845 −5.68/−3.77 1.31/1.91 0.15/0.33 — BGBC 113
P111 699/699 −5.60/−3.71 1.23/1.89 0.19/0.088 — BGBC 114
P112 711/698 −5.71/−3.70 1.22/2.01 0.10/0.075 — BGBC 114
P113 — −5.32/−4.05 1.27/— 1.92/— — BGBC 115
P114 787/787 −5.16/−3.58 1.31/1.58 1.55/0.021 — BGTC 116
P115 788/781 −5.24/−3.58 1.29/1.67 1.79/0.087 — BGTC 116
P116 — −5.47/−3.79 1.55/1.68 0.055/0.069 — TGBC 117
P117 — −5.39/−3.77 1.52/1.62 0.10/0.14 — TGBC 117
P118 —/850 −5.40/−4.40 1.01/— —/10−5 — BGTC 119
P119 —/927 −5.20/−4.20 1.01/— —/0.03 — BGTC 119
P120 —/1128 −5.00/−4.20 0.84/— —/0.001 — BGTC 119
P121 690/— −5.99/−4.49 0.89/1.50 —/0.18 — — 120
P122 693/707 −5.25/−3.77 1.48/— —/0.85 — TGBC 122
P123 384/390 −5.55/−3.91 1.63/1.64 — 9.42 (ITO/PEDOT:PSS/PffBT4T-2OD:PCBM/polymer/Ag) 125
P124 385/391 −5.47/−4.18 1.56/1.29 — 10.1 (ITO/PEDOT:PSS/PffBT4T-2OD:PCBM/polymer/Ag) 125
P125 713/698 −5.84/−3.81 —/2.03 1.70/8.50 — TGBC 127
P126 666/664 −6.20/−3.88 —/2.32 —/3.50 — TGBC 127
P127 682/683 −5.90/−3.77 —/2.13 0.70/3.10 — TGBC 127
P128 673/669 −6.24/−3.85 —/2.39 —/2.20 — TGBC 127
P129 —/676 −5.71/−3.80 1.50/1.91 0.003/3.95 — TGBC 128
P130 —/917 −5.40/−3.87 1.08/1.53 0.008/7.37 — TGBC 128
P131 — −5.60/−4.40 1.20/— 0.10/0.27 — BGTC 129
P132 833/814 −5.60/−4.00 —/1.60 — 5.57 (ITO/PEDOT: PSS/BDDT:polymer/Ca/Al) 130
P133 — −6.00/−4.20 —/1.80 —/5.60 × 10−3 — BGTC 131
P134 — −6.05/−4.22 —/1.83 —/0.12 — BGTC 131
P135 — −6.05/−4.22 —/1.83 —/0.55 — BGTC 131
P136 500/515 −5.41/−3.29 2.00/2.12 — 5.04 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 132
P137 502/518 −5.47/−3.46 1.98/2.01 — 6.35 (ITO/PEDOT:PSS/polymer:PCBM/Ca/Al) 132
P138 607/610 −6.05/−4.01 1.71/2.04 —/0.11 7.52 BGTC (ITO/ZnO/PTB7−Th:polymer/MoO3/Ag) 133
P139 638/640 −5.76/−3.96 1.59/1.80 8.70 × 10−4/1.79 × 10−3 — BGTC 133
P140 440/444 −5.40/−3.88 1.06/1.52 0.02/— — BGBC 134
P141 524/— −5.99/−3.33 2.07/2.66 —/0.039 — TGBC 135
P142 551/— −5.76/−3.27 1.94/2.49 —/0.029 — TGBC 135
P143 592/— −5.85/−3.38 1.87/2.47 —/0.19 — TGBC 135
P144 —/562 −5.90/−3.96 1.74/1.94 — 6.85 (ITO/PEDOT:PSS/PBDT-TS1:polymer/Mg/Al) 137
P145 427/432 −5.97/−3.97 1.74/2.00 — 3.52 (ITO/PEDOT:PSS/PTB7-Th:polymer/Ca/Al) 138
P146 407/410 −6.18/−3.95 1.86/2.23 — 0.97 (ITO/PEDOT:PSS/PTB7-Th:polymer/Ca/Al) 138
P147 408/413 −5.73/−4.04 1.56/1.69 — 1.43 (ITO/PEDOT:PSS/PTB7-Th:polymer/Ca/Al) 138
P148 444/625 −5.56/−3.70 1.86/— 0.04/0.30 — TGBC 139
P150 498/755 −5.01/−3.70 1.31/— 3 × 10−3/0.03 — TGBC 139
P151 380/— −6.00/−3.80 1.79/2.20 — 4.70 (ITO/PEDOT:PSS/PTB7-Th:polymer/Ca/Al) 140
P152 — −5.82/−4.12 1.70/— — 6.39 (ITO/PEDOT:PSS/PTB7-Th:polymer/Au) 141
P153 — −5.94/−4.15 1.79/— — 5.35 (ITO/PEDOT:PSS/PTB7-Th:polymer/Au) 141
P154 402/547 −5.94/−4.03 1.91/— — 8.59 (ITO/ZnO/PTB7-Th:polymer/V2O5/Al) 142
P155 — −5.45/−3.80 1.29/1.65 —/0.30 — BGTC 144
P156 — −5.14/−3.74 0.94/1.40 —/0.09 — BGTC 144
P157 — — — — 0.03 (ITO/PEDOT:PSS/polymer/Al) 145
P158 — — — — 0.03 (ITO/PEDOT:PSS/polymer/Al) 145
P159 491/507 −5.39/−3.36 2.03/— — 9.48 (ITO/PEDOT:PSS/polymer:IDIC/Au) 147
P160 510/516 −5.25/−3.25 2.00/— — 8.31 (ITO/PEDOT:PSS/polymer:IDIC/Au) 147
P161 575/583 −5.55/−3.80 1.75/— 0.63(0.21c)/— 13.3 TGBC (ITO/PEDOT:PSS/polymer:IT-4F/PDINO/Al) 148
P162 580/580 −5.63/−3.86 1.77/— 0.93(0.23c)/— 12.7 TGBC (ITO/PEDOT:PSS/polymer:IT-4F/PDINO/Al) 148
P163 551/587 −5.34/−3.46 1.81/— — 8.63 (ITO/PEDOT:PSS/polymer:PCBM/PFN-Br/Al) 149
P164 545/608 −5.90/−3.60 1.80/2.30 — 10.2 (ITO/PEDOT:PSS/polymer:ITIC/PDINO/Al) 150
P165 578/598 −5.97/−3.63 1.81/2.34 — 12.1 (ITO/PEDOT:PSS/polymer:ITIC/PDINO/Al) 150
P166 — −5.56/−3.75 1.80/1.81 — 9.30 (ITO/PEDOT:PSS/polymer:PBDTTT-C-T:PCBM/Ca/Al) 151
P167 518/567 −5.65/−3.90 1.75/— — 9.21 (ITO/ZnO/polymer:PCBM/MoO3/Ag) 153
P168 533/593 −5.39/−3.59 1.80/— 0.74/— — TGBC 154
P169 480/534 −5.67−/3.74 1.93/— 0.32/— — TGBC 154
P170 610/630 −5.20/−3.45 1.78/1.75 — 14.2 (ITO/PEDOT:PSS/polymer:Y6/PFN-Br/Ag) 155
P171 —/578 −6.18/−4.05 —/2.13 —/0.06 — BGTC 156
P172 —/535 −6.15/−4.00 —/2.15 —/2.55 — BGTC 156
P173 —/641 −5.48/−3.17 1.78/— 0.06/— 5.60 BGTC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 158
P174 —/660 −5.49/−3.25 1.71/— 0.05/— 8.00 BGTC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 158
P175 —/654 −5.62/−3.20 1.73/— 0.03/0.02 2.40 BGTC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 158
P176 —/602 −6.02/−3.36 1.91/— —/0.05 0.05 BGTC (ITO/ZnO/polymer:PCBM/MoOx/Ag) 158
P177 587/588 −5.43/−3.45 1.98/— —/3.10 6.67 TGBC (ITO/PEDOT:PSS/PTB7-Th:polymer/LiF/Al) 159
P178 606/616 −5.43/−3.55 1.88/— —/1.23 8.61 TGBC (ITO/PEDOT:PSS/PTB7-Th:polymer/LiF/Al) 159
P179 — −5.27/−3.43 1.84/— —/1.13 6.85 TGBC (ITO/PEDOT:PSS/PTB7-Th:polymer/ETL/Al) 160
P180 — −5.28/−3.30 1.98/— —/0.84 0.03 TGBC (ITO/PEDOT:PSS/PTB7-Th:polymer/ETL/Al) 160
P181 —/588 −6.08/−3.50 1.96/— —/2.73 6.50 TGBC (ITO/PEDOT:PSS/PTB7-Th:polymer/LiF/Al) 161
P182 — −5.94/−3.46 1.74/2.48 — 8.10 (ITO/PEDOT:PSS/active layer/LiF/Al) 162
P183 — −5.78/−3.77 2.01/— —/1.61 — TGBC 163
P184 — −5.97/−4.09 1.88/— — 19.5 PVSCs (ITO/PTAA/perovskite/polymer/BCP/Ag) 164
P185 — −5.79/−4.01 1.78/— — 20.8 PVSCs (ITO/PTAA/perovskite/polymer/BCP/Ag) 164
P186 628/666 −5.44/−3.05 1.65/2.39 — 8.61 (ITO/ZnO/polymer:PCBM/MoO3/Ag) 165
P187 618/658 −5.41/−3.01 1.67/2.40 — 10.2 (ITO/ZnO/polymer:PCBM/MoO3/Ag) 165
P188 590/635 −5.48/−2.99 1.72/2.49 — 8.47 (ITO/ZnO/polymer:PCBM/MoO3/Ag) 165
P189 643/630 −5.59/−3.66 1.60/1.93 1.17 × 10−2/2.78 × 10−3 — TGBC 166
P190 594/585 −5.85/−3.75 1.62/2.10 1.38 × 10−1/7.39 × 10−2 — TGBC 166
P191 560/587 −5.70/−3.68 1.67/2.02 7.42 × 10−3/8.04 × 10−4 — TGBC 166
a

The frontier energy levels calculated from the cyclic voltammetry or UPS.

b

The performance of the polymer having additives.

c

The mobilities extracted in the linear region.