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. 2021 Apr 7;12(20):6969–6976. doi: 10.1039/d1sc00811k

Selected bond lengths and prism heights h (both in Å) in compounds 3–6. Additional bond lengths are presented in the ESI.

3 4 5 6
h 1 3.976(1) 3.918(1) 3.429(1) 3.370(1)
h 2 2.759(2) 2.815(2) 3.525(1) 3.663(1)
h 3 2.932(1) 2.934(1) 3.295(1) 3.201(1)
h long/hshort 1.44 1.39 1.07 1.14
Ge–Geshort 2.5038(8) (Ge1–Ge2) 2.5046(8) (Ge1–Ge2) 2.5031(9) (Ge6–Ge9) 2.5128(7) (Ge3–Ge7)
Ge–Gelong 2.9322(8) (Ge7–Ge8) 2.9324(8) (Ge7–Ge8) 2.715(1) (Ge4–Ge8) 2.7396(7) (Ge4–Ge8)
Ge1–C1 1.995(5) 2.007(5) 1.984(6) 1.997(4)
Ge3–Si1 2.396(2) 2.392(2) 2.381(2) 2.369(1)
Ge5–Si5 or Ge9–Si5 2.395(2) 2.403(2) 2.383(2) 2.381(1)