Table 1. Summary of Kinetic Analysesa.
well code | NDIC well number | Eaa (kJ/mol) | ln(Aa) -m.y | TH | C | No. | Eac (kJ/mol) | ln(Ac) -m.y | Eac1 (kJ/mol) | ln(Ac1) -m.y |
---|---|---|---|---|---|---|---|---|---|---|
A | 17,043 | 206.77 | 60.77 | 721.29 | –157.64 | 7 | 204.42 | 60.38 | 213.08 | 61.82 |
B | 16,160 | 227.48 | 63.20 | 741.61 | –162.20 | 8 | 226.66 | 63.07 | 218.97 | 61.82 |
C | 17,023 | 215.21 | 61.68 | 730.20 | –159.27 | 4 | 215.15 | 61.68 | 216.03 | 61.82 |
D | 16,532 | 214.93 | 61.81 | 727.92 | –159.12 | 14 | 211.36 | 61.22 | 215.02 | 61.82 |
E | 16,862 | 204.28 | 60.14 | 723.98 | –157.70 | 1 | 209.18 | 60.95 | 214.40 | 61.82 |
F | 21,668 | 219.33 | 61.32 | 751.19 | –163.61 | 1 | 241.43 | 64.85 | 222.48 | 61.82 |
G | 22,572 | 231.63 | 64.30 | 733.81 | –160.64 | 1 | 216.99 | 61.90 | 216.52 | 61.82 |
H | 17,434 | 203.95 | 59.71 | 731.51 | –159.20 | 1 | 217.95 | 62.01 | 216.77 | 61.82 |
I | 5088 | 216.89 | 61.59 | 736.98 | –160.47 | 4 | 223.96 | 62.74 | 218.32 | 61.82 |
J | 13,098 | 237.32 | 64.36 | 736.97 | –157.01 | 14 | 237.31 | 64.36 | 221.77 | 61.82 |
K | 8177 | 218.92 | 62.78 | 721.33 | –157.59 | 1 | 204.71 | 60.41 | 213.16 | 61.82 |
Eaa and ln(Aa) are solutions to the Kissinger equation found by including all experiments for each well combined into a single analysis. Each analysis contains seven experiments using 2, 2, 5, 10, 20, 50, and 50 °C/min. Heating Rates. The harmonic mean of the peak reaction temperatures (TH) for each set of analyses is used in eq 3to “correct” Eaa and ln(Aa) to Eac and ln(Ac) with eqs 5 and 7, respectively.