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. 2021 Apr 13;6(16):10679–10690. doi: 10.1021/acsomega.1c00048

Table 1. Summary of Kinetic Analysesa.

well code NDIC well number Eaa (kJ/mol) ln(Aa) -m.y TH C No. Eac (kJ/mol) ln(Ac) -m.y Eac1 (kJ/mol) ln(Ac1) -m.y
A 17,043 206.77 60.77 721.29 –157.64 7 204.42 60.38 213.08 61.82
B 16,160 227.48 63.20 741.61 –162.20 8 226.66 63.07 218.97 61.82
C 17,023 215.21 61.68 730.20 –159.27 4 215.15 61.68 216.03 61.82
D 16,532 214.93 61.81 727.92 –159.12 14 211.36 61.22 215.02 61.82
E 16,862 204.28 60.14 723.98 –157.70 1 209.18 60.95 214.40 61.82
F 21,668 219.33 61.32 751.19 –163.61 1 241.43 64.85 222.48 61.82
G 22,572 231.63 64.30 733.81 –160.64 1 216.99 61.90 216.52 61.82
H 17,434 203.95 59.71 731.51 –159.20 1 217.95 62.01 216.77 61.82
I 5088 216.89 61.59 736.98 –160.47 4 223.96 62.74 218.32 61.82
J 13,098 237.32 64.36 736.97 –157.01 14 237.31 64.36 221.77 61.82
K 8177 218.92 62.78 721.33 –157.59 1 204.71 60.41 213.16 61.82
a

Eaa and ln(Aa) are solutions to the Kissinger equation found by including all experiments for each well combined into a single analysis. Each analysis contains seven experiments using 2, 2, 5, 10, 20, 50, and 50 °C/min. Heating Rates. The harmonic mean of the peak reaction temperatures (TH) for each set of analyses is used in eq 3to “correct” Eaa and ln(Aa) to Eac and ln(Ac) with eqs 5 and 7, respectively.