Table 1. Parameters of Mössbauer Spectra of [Ni0.4Cu0.2Zn0.4](Fe2–xDyx)O4 (0.00 ≤ x ≤ 0.04) SFNPs (Hhf: Hyperfine Magnetic Field; I.S: Isomer Shift; Q.S: Quadrupole Splitting; and Area: Relative Area)a.
| X | spectral component | I.S. (±0.01) (mm s–1) | Q.S. (±0.02) (mm s–1) | Hhf (±0.1) (T) | area (%) |
|---|---|---|---|---|---|
| 0.00 | Sx-A: Fe+3 | 0.277 | 0.013 | 45.212 | 19.489 |
| Sx-B1: Fe+3 | 0.291 | –0.09 | 42.486 | 25.434 | |
| Sx-B2: Fe+3 | 0.318 | –0.027 | 37.616 | 55.077 | |
| 0.01 | Sx-A: Fe+3 | 0.289 | 0.024 | 44.177 | 19.919 |
| Sx-B1: Fe+3 | 0.305 | 0.01 | 40.829 | 29.18 | |
| Sx-B2: Fe+3 | 0.315 | –0.052 | 35.776 | 50.901 | |
| 0.02 | Sx-A: Fe+3 | 0.277 | 0.005 | 45.207 | 24.88 |
| Sx-B1: Fe+3 | 0.318 | –0.019 | 41.777 | 19.804 | |
| Sx-B2: Fe+3 | 0.321 | –0.033 | 36.527 | 55.316 | |
| 0.03 | Sx-A: Fe+3 | 0.29 | –0.007 | 42.757 | 35.078 |
| Sx-B1: Fe+3 | 0.319 | –0.004 | 37.275 | 22.349 | |
| Sx-B2: Fe+3 | 0.344 | 0.012 | 30.497 | 42.573 | |
| 0.04 | Sx-A: Fe+3 | 0.282 | 0.02 | 43.458 | 24.748 |
| Sx-B: Fe+3 | 0.318 | –0.027 | 36.647 | 28.412 | |
| Sx-B2: Fe+3 | 0.341 | –0.009 | 25.894 | 37.381 | |
| Db: Fe+3 | 0.328 | 0.617 | 9.4601 |
Three ferromagnetic sextets have been applied to fit the spectrum, A for the tetrahedral sites and B1 and B2 for the octahedral positions for samples.