Table 1. Relation between Initial (ini) and Water-Saturated (eq) TOMAC Molarity in Toluene after Equilibration with 0.1 mol L–1 LiCla.
[TOMAC]ini (mol L–1) | [TOMAC]eq (mol L–1) | densityorg,eq (g mL–1) |
---|---|---|
0.21 | 0.21 | 0.868 |
0.43 | 0.41 | 0.874 |
0.64 | 0.60 | 0.880 |
0.85 | 0.78 | 0.886 |
1.06 | 0.94 | 0.891 |
1.28 | 1.11 | 0.897 |
1.49 | 1.26 | 0.902 |
1.71 | 1.39 | 0.907 |
1.92 | 1.51 | 0.912 |
2.14 | 1.60 | 0.918 |
The equilibrium TOMAC concentration is significantly reduced by the presence of large amounts of water in the organic phase. In addition, the density of the organic phase at 25 °C at equilibrium is given.