Table 1. Optimization of the Reaction Conditions.
| entry | catalyst | conv. (%) | yield (%)a |
|---|---|---|---|
| 1 | KF | 46 | 42 |
| 2 | KCl | 23 | 19 |
| 3 | KBr | 11 | 2 |
| 4 | KI | <5 | trace |
| 5 | NaF | 27 | 22 |
| 6 | CsF | 65 | 55 |
| 7 | MgF2 | <5 | trace |
| 8 | TBAF | >95 | 50 |
| 9 | TBAT | 94 | 75 |
| 10b | TBAT | 71 | 65 |
| 11b,c | TBAT | >95 | 93 (89)d |
Determined by 1H NMR analysis using mesitylene as internal standard.
PTFE vessel was used instead of glassware.
The reaction was carried out for 3 h.
Isolated yield.
