Charge-carrier mobility
changes indicative of excited-state localization.
(a) Temperature dependence of the localization rate (kloc, blue crosses) within the two-state mobility model
for Cs2AgBiBr6. The red dashed line indicates
the mean value, with its uncertainty represented by the red shaded
area. (b) Temperature dependence of the effective charge-carrier mobilities
associated with the delocalized (μdeloc, green) and
localized (μloc, blue) states. Power-law fits are
plotted as solid lines in the corresponding colors, with their exponents
(p) displayed alongside. The data points for μdeloc at the lowest two temperatures were not included in the
fit as the power-law model becomes unphysical in this region, indicated
by the dashed green line. The mobilities are “effective”
since the photon-to-charge branching ratio, ϕ, is not necessarily
1.