. 2021 Apr 14;40(8):1086–1103. doi: 10.1021/acs.organomet.1c00059

Table 3. HY of Carbonyl Compounds (2 M) with Complexes 7, 9, 10, and 19 under H₂ with KOtBu (2 mol %) after 16 h.

entry	complex	substrate	S/C	solvent	T (°C)	p(H₂) (atm)	conversion^a (%)	alcohol^a (%)	byproducts^a (%)
1	7	a	10000	EtOH	40	30	99	99
2	10	a	10000	EtOH	40	30	99	99
3	19	a	10000	EtOH	70	30	40	40
4	9	f	1000	MeOH	50	20	56	55
5	9	g	1000	MeOH	50	20	>99	93	6^b

The HY experiments were carried out in an eight-vessel Endeavor Biotage system, and the conversions were determined by GC analysis.

3-phenylpropan-1-ol.

Table 3. HY of Carbonyl Compounds (2 M) with Complexes 7, 9, 10, and 19 under H2 with KOtBu (2 mol %) after 16 h.